Cyclopentadienylruthenium π Complexes of Subphthalocyanines: A "Drop-Pin" Approach To Modifying the Electronic Features of Aromatic Macrocycles

被引：43
作者：
Caballero, Esmeralda [1 ]
Fernandez-Ariza, Javier [1 ]
Lynch, Vincent M. [2 ,3 ]
Romero-Nieto, Carlos [4 ,5 ]
Salome Rodriguez-Morgade, M. [1 ]
Sessler, Jonathan L. [2 ,3 ]
Guldi, Dirk M. [4 ,5 ]
Torres, Tomas [1 ,6 ]
机构：
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
[2] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
[3] Univ Texas Austin, Inst Cellular & Mol Biol, Austin, TX 78712 USA
[4] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany
[5] Univ Erlangen Nurnberg, ICMM, D-91058 Erlangen, Germany
[6] IMDEA Nanociencia, Madrid 28049, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 45期
基金：
美国国家科学基金会;
关键词：
arene ligands; pi complexes; ruthenium; subphthalocyanines; subporphyrazines; PHOTOINDUCED CHARGE-TRANSFER; ENERGY-TRANSFER; METALLOPORPHYRINS; SUBPORPHYRINS; NONPLANAR; VERSATILE;
D O I：
10.1002/anie.201206111
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Facing facts: Coordination of Cp*Ru (Cp*=C5Me 5) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11337 / 11342
页数：6
相关论文
共 44 条
[1]   Electrochemical and EPR studies of the corannulene ruthenium(II) sandwich complex [(η6-C6Me6)Ru(η6-C20H10)](SbF6)2 [J].
Angelici, Robert J. ;
Zhu, Bolin ;
Fedi, Serena ;
Laschi, Franco ;
Zanello, Piero .
INORGANIC CHEMISTRY, 2007, 46 (25) :10901-10906
[2]   SYNTHESES AND REACTIVITIES OF INDOLE AND INDOLYL COMPLEXES OF (CYMENE)RUTHENIUM(II) [J].
CHEN, S ;
CARPEROS, V ;
NOLL, B ;
SWOPE, RJ ;
DUBOIS, MR .
ORGANOMETALLICS, 1995, 14 (03) :1221-1231
[3]   Subphthalocyanines:: Singular nonplanar aromatic compounds-synthesis, reactivity, and physical properties [J].
Claessens, CG ;
González-Rodríguez, D ;
Torres, T .
CHEMICAL REVIEWS, 2002, 102 (03) :835-853
[4]   Subphthalocyanine enantiomers:: first resolution of a C3 aromatic compound by HPLC [J].
Claessens, CG ;
Torres, T .
TETRAHEDRON LETTERS, 2000, 41 (33) :6361-6365
[5]   π-complexes of phthalocyanines and metallophthalocyanines [J].
Contakes, SM ;
Beatty, ST ;
Dailey, KK ;
Rauchfuss, TB ;
Fenske, D .
ORGANOMETALLICS, 2000, 19 (23) :4767-4774
[6]   Metalloporphycenes: Synthesis and Characterization of (Pentamethylcyclopentadienyl)ruthenium Sitting-Atop and π-Complexes [J].
Cuesta, Luciano ;
Karnas, Elizabeth ;
Lynch, Vincent M. ;
Chen, Ping ;
Shen, Jing ;
Kadish, Karl M. ;
Ohkubo, Kei ;
Fukuzumi, Shunichi ;
Sessler, Jonathan L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (37) :13538-13547
[7]   (Pentamethylcyclopentadienyl)ruthenium π-Complexes of Metalloporphyrins: Platforms with Novel Photo- and Electrochemical Properties [J].
Cuesta, Luciano ;
Karnas, Elizabeth ;
Lynch, Vincent M. ;
Sessler, Jonathan L. ;
Kajonkijya, Wiroaj ;
Zhu, Weihua ;
Zhang, Min ;
Ou, Zhongping ;
Kadish, Karl. M. ;
Ohkubo, Kei ;
Fukuzumi, Shunichi .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (33) :10206-10210
[8]   π-Metal complexes of tetrapyrrolic systems. A novel coordination mode in "porphyrin-like'' chemistry [J].
Cuesta, Luciano ;
Sessler, Jonathan L. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (09) :2716-2729
[9]   pi-complexes of metalloporphyrins as model intermediates in hydrodemetallation (HDM) catalysis [J].
Dailey, KK ;
Rauchfuss, TB .
POLYHEDRON, 1997, 16 (18) :3129-3138
[10]   Metalloporphyrins as ligands: Synthesis and characterization of [(eta(6)-cymene)-Ru{eta(5)-Ni(OEP)}](2+) [J].
Dailey, KK ;
Yap, GPA ;
Rheingold, AL ;
Rauchfuss, TB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (16) :1833-1835
12345