Ru(II)-based metallosurfactant inverted aggregates

被引：69

作者：

Domínguez-Gutiérrez, D ^{[1
]}

Surtchev, M ^{[1
]}

Eiser, E ^{[1
]}

Elsevier, CJ ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

来源：

NANO LETTERS | 2006年 / 6卷 / 02期

关键词：

D O I：

10.1021/nl051944v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Knowing the advantages of incorporating a transition metal into interfaces, we report on the first inverted aggregates formed using metallosurfactants. The metallosurfactant possesses four long linear tails that account for the shielding of the polar headgroup in apolar solvents. The nature of the so-formed aggregates changes dramatically from inverted vesicles (toluene) to inverted micelles (hexane). The size of the aggregates was determined using dynamic light scattering. Atomic force microscopy allowed us to study the dry structure of the vesicles on a glass surface.

引用

页码：145 / 147

页数：3

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