Gamma ray induced modifications of quaternary silicate glasses

被引:30
作者
Sandhu, A. K. [1 ]
Singh, S. [1 ]
Pandey, P. [2 ]
机构
[1] Guru Nanak Dev Univ, Dept Phys, Amritsar 143005, Punjab, India
[2] Thapar Univ, Sch Phys & Mat Sci, Patiala 147004, Punjab, India
关键词
D O I
10.1088/0022-3727/41/16/165402
中图分类号
O59 [应用物理学];
学科分类号
摘要
This paper reports the effects of gamma ray irradiation and glass composition on the optical and infrared spectra of quaternary silicate glasses. Experimental results reveal the formation of radiation-induced absorption bands in the visible region attributed to nonbridging oxygen hole centres. The band gap energy and the width of the energy tail above the mobility gap have been measured before and after irradiation. The decrease in the energy gap values has been discussed in terms of radiation-induced Structural modifications and the glass composition. Changes in the infrared spectra with progressive gamma irradiation have been observed and explained with reference to the radiolysis of Si-O-Si bonds.
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页数:6
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共 35 条
  • [1] [Anonymous], 1974, AMORPHOUS LIQUID SEM
  • [2] Arbuzov VI, 1996, GLASS PHYS CHEM+, V22, P477
  • [3] Azhniuk Yu. M., 2002, Fizika A, V11, P51
  • [4] Effects of irradiation on transmittance of cerium doped germanate glasses in the ultraviolet and visible regions
    Baccaro, S
    Cecilia, A
    Chen, G
    Du, Y
    Montecchi, M
    Wang, H
    Wang, S
    [J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2002, 191 : 352 - 355
  • [5] Bartoll J, 2000, PHYS CHEM GLASSES, V41, P140
  • [6] Bishay A., 1970, Journal of Non-Crystalline Solids, V3, P54, DOI 10.1016/0022-3093(70)90106-7
  • [7] Chakradhar RPS, 2003, J PHYS CHEM SOLIDS, V64, P641
  • [8] Doremus RobertH., 1994, GLASS SCI
  • [9] Duffy JA, 2001, PHYS CHEM GLASSES, V42, P151
  • [10] SHORT-TIME REACTIONS OF A NA2O-CAO-SIO2 GLASS WITH WATER AND SALT-SOLUTIONS
    DUNKEN, H
    DOREMUS, RH
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 92 (01) : 61 - 72