Photoelectrolysis of HBr and HI using a monolithic combined photoelectrochemical photovoltaic device

被引：20

作者：

Khaselev, O ^{[1
]}

Turner, JA ^{[1
]}

机构：

[1] Natl Renewable Energy Lab, Golden, CO 80401 USA

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 1999年 / 2卷 / 07期

关键词：

D O I：

10.1149/1.1390820

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The photoelectrolysis of HBr and HI using a p-GaInP2(Pt)/GaAs photoelectrochemical/photovoltaic device is demonstrated. The device is a photoelectrochemical cell, voltage-biased with an integrated photovoltaic device. This device splits these acids directly on illumination, using light as the only energy input. Additionally, for these compounds, the device can simultaneously produce electrical energy. The HBr and HI decomposition efficiency for this system, based on the short-circuit current and the chemical potential of each compound, is 8.1 and 2.6%, respectively. The total conversion efficiency, including the cogenerated electrical energy, is 11.2 and 9.65%, respectively. (C) 1999 The Electrochemical Society. S1099-0062(99)02-011-8. All rights reserved.

引用

页码：310 / 312

页数：3

共 15 条

[1] 29.5-PERCENT-EFFICIENT GALNP/GAAS TANDEM SOLAR-CELLS
BERTNESS, KA
KURTZ, SR
FRIEDMAN, DJ
KIBBLER, AE
KRAMER, C
OLSON, JM
[J]. APPLIED PHYSICS LETTERS, 1994, 65 (08) : 989 - 991
[2] BERTNESS KA, 1994, P 12 NREL PHOT PROG, P100
[3] SEMICONDUCTOR ELECTRODES .36. CHARACTERISTICS OF N-MOSE2, N-WSE2 AND P-WSE2 ELECTRODES IN AQUEOUS-SOLUTION
FAN, FRF
BARD, AJ
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (05) : 945 - 952
[4] FARENBRUCH A, 1983, FUNDAMENTALS SOLAR C, P211
[5] A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting
Khaselev, O
Turner, JA
[J]. SCIENCE, 1998, 280 (5362) : 425 - 427
[6] Kilby JS, 1977, US Patent, Patent No. [4,021,323, 4021323]
[7] KILBY JS, 1970, Patent No. 4136436
[8] Lathrop J. W., 1978, US Pat., Patent No. [4 100 051, 4100051]
[9] SPONTANEOUS PHOTOELECTROLYSIS OF HBR AND HL
LEVYCLEMENT, C
HELLER, A
BONNER, WA
PARKINSON, BA
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (08) : 1701 - 1705
[10] HYDROGEN EVOLUTION AND IODINE REDUCTION ON AN ILLUMINATED N-P JUNCTION SILICON ELECTRODE AND ITS APPLICATION TO EFFICIENT SOLAR PHOTOELECTROLYSIS OF HYDROGEN IODIDE
NAKATO, Y
EGI, Y
HIRAMOTO, M
TSUBOMURA, H
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (19) : 4218 - 4222

← 1 2 →