Catalyzed Light Hydride Nanomaterials Embedded in a Micro-Channels Hydrogen Storage Container

被引:6
作者
Dehouche, Zahir [1 ]
Peretti, Hernan A. [2 ]
Yoo, Yeong [3 ]
Belkacemi, Khaled [1 ]
Goyette, Jacques [4 ]
机构
[1] Univ Laval, Dept Soil Sci & Agri Food Engn, Quebec City, PQ G1K 7P4, Canada
[2] Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, RN, Argentina
[3] NRC, Inst Chem Proc & Environm Technol, Ottawa, ON K1A 0R6, Canada
[4] UQTR, Inst Rech Hydrogene, Trois Rivieres, PQ G9A 5H7, Canada
关键词
Hydrogen storage materials; alloy catalysts; nanostructures; high-energy ball milling; micro-channels container; X-ray diffraction; SORPTION PROPERTIES; GRAPHITE; ALLOYS; CARBON; DESORPTION; KINETICS;
D O I
10.2174/187221009788490059
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Activated alloys synthesized by arc-melting were examined as catalysts for improving the hydrogen sorption characteristics of nanostructured magnesium hydride, proposed as a reversible hydrogen storage material. The MgH2-catalyst absorbing materials were prepared by ball milling of pure MgH2 with hydrided Zr47Ni53, Zr9Ni11, and other alloys investigated. The nanostructured MgH2-intermetallic systems were tested at 250 degrees C and catalyst addition of eutectoid Zr47Ni53 resulted in the fastest desorption time and highest initial desorption rate. The catalyzed Mg-hydride with activated Zr9Ni11 and Zr7Ni10 phases showed fast desorption kinetics. Moreover, the results demonstrated that the composition of dispersed ZrxNiy catalysts has a strong influence on the amount of accumulated hydrogen and desorption rate of Mg-nanocomposite. Part two covers advanced micro-channels hydrogen storage module design based on the results of semi-empirical computer simulations of heat and mass transfers in the container. The micro-channels reservoir concept offers many advantages over the conventional metal hydride hydrogen storage system. It is a micro-structured system that can pack a lot of power into a small space and dissipate effectively the heat of the sorption reactions. This review summarize recent patents related to CNTS.
引用
收藏
页码:116 / 134
页数:19
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