Storage stability of three organophosphorus pesticides on cucumber samples for analysis

被引:41
作者
Bian, Yanli [1 ]
Liu, Fengmao [1 ]
Chen, Fei [1 ]
Sun, Pan [1 ]
机构
[1] China Agr Univ, Coll Sci, 2 Yuanmingyuan West Rd, Beijing 100193, Peoples R China
基金
中国国家自然科学基金;
关键词
Residue sample; Storage stability; Organophosphorus pesticide; Influencing factors; Cucumber; DEGRADATION; RESIDUES; HYDROLYSIS; MALATHION; WHEAT;
D O I
10.1016/j.foodchem.2018.01.008
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The residue sample storage stability of three organophosphorus pesticides, dichlorvos, diazinon, and malathion, under different conditions was investigated. The storage conditions studied included storage time, temperature, and sample form. The addition of extra enzyme to the samples was also studied to investigate its effect on stability. It was found that malathion was more unstable than dichlorvos and diazinon, there was an over 70% loss in 90 days even at -20 degrees C in coarsely chopped form. The pesticide residues were more stable when the cucumber was in homogenate form than coarsely chopped. Furthermore, the addition of catalase increased the degradation of malathion, where there was more decomposition with increasing levels of catalase. However, there was no obvious relationship between degradation of dichlorvos and diazinon and catalase concentration. Overall, this study revealed factors that can be optimized to increase the storage stability of organophosphorus pesticides, where enzyme was one of the main influencing factors.
引用
收藏
页码:230 / 235
页数:6
相关论文
共 40 条
[1]   Time-dependent integrity during storage of natural surface water samples for the trace analysis of pharmaceutical products, feminizing hormones and pesticides [J].
Aboulfadl, Khadija ;
De Potter, Cyril ;
Prevost, Michele ;
Sauve, Sebastien .
CHEMISTRY CENTRAL JOURNAL, 2010, 4
[2]   Stability of organophosphate and pyrethroid pesticides on wheat in storage [J].
Afridi, IAK ;
Parveen, Z ;
Masud, SZ .
JOURNAL OF STORED PRODUCTS RESEARCH, 2001, 37 (02) :199-204
[3]  
Ambrus a., 2016, FAO MANUAL SUBMISSIO, P225
[4]  
[Anonymous], 2007, OECD GUID TEST CHEM, V1, P1, DOI [10.1787/9789264061927-en, DOI 10.1787/9789264061927-EN]
[5]   Effect of storage temperature on the degradation of dimethoate in fortified orange and peach juices [J].
Athanasopoulos, P ;
Kyriakidis, NB ;
Georgitsanakou, I .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2000, 48 (10) :4896-4899
[6]   Degradation of methamidophos on soultanina grapes on the vines and during refrigerated storage [J].
Athanasopoulos, PE ;
Pappas, C ;
Kyriakidis, NV ;
Thanos, A .
FOOD CHEMISTRY, 2005, 91 (02) :235-240
[7]   Residue contents of DDVP (Dichlorvos) and diazinon applied on cucumbers grown in greenhouses and their reduction by duration of a pre-harvest interval and post-harvest culinary applications [J].
Cengiz, MF ;
Certel, M ;
Göçmen, H .
FOOD CHEMISTRY, 2006, 98 (01) :127-135
[8]  
Çetinus SA, 2000, ENZYME MICROB TECH, V26, P497, DOI 10.1016/S0141-0229(99)00189-1
[9]  
Cheng TC, 2000, NATO SCI PRT 1 DISAR, V33, P243
[10]   Feasibility study of a reference material for water chemistry: Long term stability of triazine and phenylurea residues stored in vials or on polymeric sorbents [J].
Deplagne, Jerome ;
Vial, Jerome ;
Pichon, Valerie ;
Lalere, Beatrice ;
Hervouet, Gilles ;
Hennion, Marie-Claire .
JOURNAL OF CHROMATOGRAPHY A, 2006, 1123 (01) :31-37