Baeyer-Villiger Oxidation Using Hydrogen Peroxide

被引：90
作者：
Uyanik, Muhammet [1 ]
Ishihara, Kazuaki [1 ,2 ]
机构：
[1] Nagoya Univ, CREST, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[2] Nagoya Univ, CREST, Japan Sci & Technol Agcy JST, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
ACS CATALYSIS | 2013年 / 3卷 / 04期
关键词：
Baeyer-Villiger oxidation; hydrogen peroxide; transition-metal catalysis; organocatalysis; tetraaryl borate salts; CHIRAL BRONSTED ACID; 3-SUBSTITUTED CYCLOBUTANONES; SODIUM TETRAKIS(3,5-TRIFLUOROMETHYLPHENYL)BORATE; PROCHIRAL CYCLOBUTANONES; STEREOSPECIFIC SYNTHESIS; AROMATIC-ALDEHYDES; REACTION SYSTEM; CYCLIC-KETONES; LEWIS ACIDITY; CATALYST;
D O I：
10.1021/cs300821u
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Baeyer-Villiger (BV) oxidation of carbonyl compounds to the corresponding esters or lactones is one of the most important transformations. We recently introduced a highly efficient and selective LiB(C6F5)(4)- or Ca[B(C6F5)(4)](2)- catalyzed BV oxidation of ketones with aqueous hydrogen peroxide to give the corresponding lactones in high yield. In this perspective article, we focus on our discovery and the development of BV oxidation reactions and cascade oxidative transformations through representative metal catalysts and organocatalysts.
引用
收藏
页码：513 / 520
页数：8
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