Synthesis and color-tunable emission studies of Y2Si3O3N4:Ce3+, Tb3+ phosphors

被引:8
作者
Zhu, Jicheng [1 ]
Qin, Shigiang [1 ]
Xia, Zhiguo [1 ]
Liu, Quanlin [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
Optical properties; Oxynitride; Phosphor; Energy transfer; ENERGY-TRANSFER; CRYSTAL-STRUCTURE; LUMINESCENCE; PHOTOLUMINESCENCE; Y3SI5N9O;
D O I
10.1016/j.ceramint.2015.06.092
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The exploration of new color-tunable materials for solid-state lighting based on InGaN semiconductors has attracted great attention. Herein a series of Ce3+, Tb3+ and Ce3+/Tb3+ co-doped Y2Si3O3N4 phosphors have been developed. The intense green emission peaking at 543 nm was observed in the Y2Si3O3N4:Ce3+,Tb3+ phosphors. Energy transfer (ET) process from Ce3+ to Tb3+ was verified via the variations of the lifetime values of Ce3+, and the ET mechanism is ascribed to the dipole-dipole interaction. The ET critical distance has been calculated by the concentration quenching method. It is believed that the Ce3+/Tb3+-activated Y2Si3O3N4 phosphors can serve as potential materials for near ultraviolet (n-UV) light emitting diode (LED). (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:12633 / 12637
页数:5
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