Ion cavities within NH4+(crown ether)[Ni(dmit)2] salts

被引：13

作者：

Akutagawa, T ^{[1
]}

Hasegawa, T

Nakamura, T

Inabe, T

Sugiura, K

Sakata, Y

Underhill, AE

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[2] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan

[3] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

[4] Univ Wales, Dept Chem, Bangor LL57 3UW, Gwynedd, Wales

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

electrocrysatllization; transport measurement; conductivity; organic conductor based on radical anion salts;

D O I：

10.1016/S0379-6779(98)00389-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Supramolecular assemblies of ammonium ions (NH4+) with crown ethers form a variety of NH4+(crown ether) supramolecular cation (SC+) structures within the range of [Ni(dmit)(2)] salts. A new pyramidai NH4+(12-crown-4) structure is found in the NH4+(12-crown4)[Ni(dmit)(2)](3)(CH3CN)(2) salt. The SC+ structures in the NH4+(crown ether)[Ni(dmit)(2)] series vary from pyramidal-, sandwich-, to disk-shaped-structures with the crown ethers 12-crown-4, 15-crown-5, and 18-crown-6, respectively.

引用

收藏

页码：1747 / 1748

页数：2

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