Synthesis of Fischer type-carbene complexes containing a coordinated thioimidate structural motif

被引：4

作者：

Cedillo-Cruz, Alberto ^{[2
]}

Carmen Ortega-Alfaro, M. ^{[1
]}

Lopez-Cortes, Jose G. ^{[2
]}

Alfredo Toscano, Ruben ^{[2
]}

Guillermo Penieres-Carrillo, J. ^{[3
]}

Alvarez-Toledano, Cecilio ^{[2
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Ciencias Nucl, Mexico City 04360, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04360, DF, Mexico

[3] UNAM, Dept Ciencias Quim, Fac Estudios Super Cuautitlan, Cuautitlan 54740, Estado De Mexic, Mexico

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 35期

关键词：

TRANSITION-METAL-COMPLEXES; BENZANNULATION REACTION; CHEMICAL MULTITALENTS; ASYMMETRIC-SYNTHESIS; AROMATIC THIOAMIDES; CARBON-ATOM; CHROMIUM; LIGANDS; ALKYNE; ANIONS;

D O I：

10.1039/c2dt31297b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper describes a tandem strategy to synthesize a series of new Fischer carbene complexes [(CO)(4)M=C[N-(CH2)(4)-]CH=C(NRR')(SR'); M = Cr, W; R = Ar, R' = Me, -(CH2)(2-)] with a thioimide or thiazoline fragment, in which the sulfur or nitrogen atom is coordinated to a metal center, depending on the nature of alkylating groups included as R'. We have trapped by protonation the proposed intermediate as the thioamide 12 [(CO)(5)W=C[N-(CH2)(4)-]CH2C(S)NHPh], which reveals the pathway of this reaction

引用

页码：10568 / 10575

页数：8

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