The formal potentials and electrode kinetics of the proton/hydrogen couple in various room temperature ionic liquids

被引：32

作者：

Meng, Yao ^{[1
]}

Aldous, Leigh ^{[1
,2
]}

Belding, Stephen R. ^{[1
]}

Compton, Richard G. ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 45期

基金：

英国工程与自然科学研究理事会;

关键词：

HYDROGEN; TRANSPORT; ELECTROCHEMISTRY; SOLVENTS; PROTONS;

D O I：

10.1039/c2cc31402a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Hydrogen evolution reaction has been quantitatively investigated at a Pt electrode in series of room temperature ionic liquids vs. Ag/Ag+ redox couple. The measured formal potentials of the H2/H+ ( HNTf2) redox couple in each RTIL reveals a dependence on the nature of anion, suggesting significant interaction between proton and anion.

引用

页码：5572 / 5574

页数：3

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