Nanocrystalline cellulose (NCC): A renewable nano-material for polyvinyl acetate (PVA) adhesive

被引:151
作者
Kaboorani, Alireza [1 ]
Riedl, Bernard [1 ]
Blanchet, Pierre [1 ,2 ]
Fellin, Marco [3 ]
Hosseinaei, Omid
Wang, Sequin [4 ]
机构
[1] Univ Laval, Dept Sci Bois & Foret, Fac Foresterie Geog & Geomat, Quebec City, PQ G1V 0A6, Canada
[2] FPInnovations, Nanotechnol Wood Prod, Quebec City, PQ G1P 4R4, Canada
[3] Ist Valorizzaz Legno & Specie Arboree I, CNR IVALSA, Consiglio Nazl Ric, I-38010 San Michele All Adige, TN, Italy
[4] Univ Tennessee, Ctr Renewable Carbon, Knoxville, TN 37996 USA
基金
加拿大自然科学与工程研究理事会;
关键词
Durable wood adhesives; Polyvinyl acetate (PVA); Nanocrystalline cellulose (NCC); Wood joints; Nanoindentation; POLYMER NANOCOMPOSITES; ELASTIC-MODULUS; BEHAVIOR; FILMS; WHISKERS; LATEX; NANOWHISKERS; PERFORMANCE; PERCOLATION; WOOD;
D O I
10.1016/j.eurpolymj.2012.08.008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study nanocrystalline cellulose (NCC) was used to improve the performance of polyvinyl acetate (PVA) as a wood adhesive. NCC was added to PVA at different loadings (1%, 2% and 3%) and the blends were used as binder for wood. Block shear tests were done to evaluate bonding strength of PVA at different conditions; dry and wet conditions, at the elevated temperature (100 degrees C). The mechanical properties of PVA film and its composites with NCC were measured by nanoindentation technique. Thermal stability and structure of nanocomposites were studied by thermogravimetric analysis and atomic force microscopy (AFM). The block shear tests demonstrate that NCC can improve bonding strength of PVA in all conditions. Hardness, modulus of elasticity (MOE) and creep of PVA film were also changed positively by the addition of NCC. Thermal stability of PVA was significantly improved as NCC was added to PVA. Structural studies revealed that variations in shear strength and other properties can be related to the quality of NCC dispersion in the PVA matrix. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1829 / 1837
页数:9
相关论文
共 51 条
[1]   Plasticized starch/tunicin whiskers nanocomposites.: 1.: Structural analysis [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2000, 33 (22) :8344-8353
[2]   Plasticized starch/tunicin whiskers nanocomposite materials.: 2.: Mechanical behavior [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2001, 34 (09) :2921-2931
[3]   Influence of surface charge on viscosity behavior of cellulose microcrystal suspension [J].
Araki, J ;
Wada, M ;
Kuga, S ;
Okana, T .
JOURNAL OF WOOD SCIENCE, 1999, 45 (03) :258-261
[4]   Nanocomposite Edible Films from Mango Puree Reinforced with Cellulose Nanofibers [J].
Azeredo, Henriette M. C. ;
Mattoso, Luiz Henrique C. ;
Wood, Delilah ;
Williams, Tina G. ;
Avena-Bustillos, Roberto J. ;
McHugh, Tara H. .
JOURNAL OF FOOD SCIENCE, 2009, 74 (05) :N31-N35
[5]   Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis [J].
Bondeson, D ;
Mathew, A ;
Oksman, K .
CELLULOSE, 2006, 13 (02) :171-180
[6]  
BONINI C, 2000, THESIS J FOURIER U G
[7]  
Cai Y, 1997, China Adhes, V2, P43
[8]  
Chen Y., 1996, NIANJIE, V17, P25
[9]   Scaling, dimensional analysis, and indentation measurements [J].
Cheng, YT ;
Cheng, CM .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2004, 44 (4-5) :91-149
[10]   Cellulose nanocrystal-filled carboxymethyl cellulose nanocomposites [J].
Choi, YJ ;
Simonsen, J .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2006, 6 (03) :633-639