The pentanuclear FeII cluster [(C5H4)6Fe5]2-:: bringing together ferrocene sandwiches and homoleptic FeII-cyclopentadienyl σ-complexes

被引：20

作者：

Sänger, I ^{[1
]}

Heilmann, JB ^{[1
]}

Bolte, M ^{[1
]}

Lerner, HW ^{[1
]}

Wagner, M ^{[1
]}

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 19期

关键词：

D O I：

10.1039/b602359b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [(fc)(3)(Li)(6)center dot(TMEDA)(2)] with FeCl2 gives the pentanuclear iron complex [(fc)(3)(Fe)(2)(Li)(2)center dot(TMEDA)(2)] featuring two ferra[1]ferrocenophane moieties bridged by a 1,1'-ferrocenediyl unit; the non-ferrocene Fe-II ions are tetra-coordinate and adopt a high-spin state.

引用

页码：2027 / 2029

页数：3

共 20 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] Nucleophilically assisted and cationic ring-opening polymerization of tin-bridged [1]ferrocenophanes [J].

Baumgartner, T ;

Jäkle, F ;

Rulkens, R ;

Zech, G ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) :10062-10070

[3] STRUCTURE OF THE NAPHTHYL IRON(II) COMPLEX FORMED IN THE REACTION OF FECL3 AND C10H7LI [J].

BAZHENOVA, TA ;

LOBKOVSKAYA, RM ;

SHIBAEVA, RP ;

SHILOVA, AK ;

GRUSELLE, M ;

LENY, G ;

DESCHAMPS, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 244 (04) :375-382

[4] Ferrocenylalanes:: Solid-state and solution structures of some new aluminum-bridged ansa-ferrocenes [J].

Braunschweig, H ;

Burschka, C ;

Clentsmith, GKB ;

Kupfer, T ;

Radacki, K .

INORGANIC CHEMISTRY, 2005, 44 (14) :4906-4908

[5] [1]FERROCENOPHANES CONTAINING A GROUP-4 TRANSITION-METAL IN THE BRIDGE - X-RAY STRUCTURE OF ONE REPRESENTATIVE [J].

BROUSSIER, R ;

DAROLD, A ;

GAUTHERON, B ;

DROMZEE, Y ;

JEANNIN, Y .

INORGANIC CHEMISTRY, 1990, 29 (10) :1817-1822

[6] Synthesis and X-ray crystal structure of a urana[1]ferrocenophane, the first tris(1,1′-ferrocenylene) metal compound [J].

Bucaille, A ;

Le Borgne, T ;

Ephritikhine, M ;

Daran, JC .

ORGANOMETALLICS, 2000, 19 (23) :4912-4914

[7] THE STRUCTURE OF THE 3-2 ADDUCT OF 1,1'-DILITHIOFERROCENE WITH TETRAMETHYLETHYLENEDIAMINE [J].

BUTLER, IR ;

CULLEN, WR ;

NI, J ;

RETTIG, SJ .

ORGANOMETALLICS, 1985, 4 (12) :2196-2201

[8] Novel heterobimetallic compounds with metal-metal bonds: The use of quinolyl-substituted metallocenes as tridentate ligands [J].

Enders, M ;

Kohl, G ;

Pritzkow, H .

ORGANOMETALLICS, 2002, 21 (06) :1111-1117

[9] Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules [J].

Henderson, KW ;

Kennedy, AR ;

Mulvey, RE ;

O'Hara, CT ;

Rowlings, RB .

CHEMICAL COMMUNICATIONS, 2001, (17) :1678-1679

[10]

Holleman A.F., 1995, LEHRBUCH ANORGANISCH

← 1 2 →