Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

被引：188

作者：

Chen, Chi ^{[1
]}

Hecht, Maxwell B. ^{[2
]}

Kavara, Aydin ^{[2
]}

Brennessel, William W. ^{[2
]}

Mercado, Brandon Q. ^{[1
]}

Weix, Daniel J. ^{[2
]}

Holland, Patrick L. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06511 USA

[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 41期

关键词：

TRANSITION-METAL-COMPLEXES; OLEFINIC DOUBLE BONDS; IRON CATALYSTS; STEREOSELECTIVE HYDROSILYLATION; HYDROSILATION REACTION; HOMOGENEOUS CATALYSIS; SILICON HYDRIDES; RECENT PROGRESS; HYDROBORATION; ISOMERIZATION;

D O I：

10.1021/jacs.5b08611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. We report a Co catalyst for anti-Markovnikov alkene hydrosilylation that can be used without added solvent at low temperatures with low loadings, and can be generated in situ from an air-stable precursor that is simple to synthesize from low-cost, commercially available materials. In addition, a mixture of Co catalysts performs a tandem catalytic alkene isomerization/hydrosilylation reaction that converts multiple isomers of hexene to the same terminal product. This regioconvergent reaction uses isomerization as a benefit rather than a hindrance.

引用

页码：13244 / 13247

页数：4

共 44 条

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Adhikari D, 2010, INORG SYN, V35, P8

[2]

[Anonymous], 2000, SILICON ORGANIC ORGA

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