Copper-catalyzed aerobic oxidative functionalization of C-H bonds of alkanes in the presence of acetaldehyde under mild conditions

被引：12

作者：

Hayashi, Yukiko ^{[1
]}

Komiya, Naruyoshi ^{[1
]}

Suzuki, Ken ^{[2
]}

Murahashi, Shun-Ichi ^{[1
,3
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

[2] Asahi Kasei Chem Corp, R&D Planning & Business Dev, Chiyoda Ku, Tokyo 1010051, Japan

[3] Okayama Univ Sci, Fac Engn, Dept Chem, Kita Ku, Okayama 7000005, Japan

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 21期

关键词：

Copper catalyst; Aerobic oxidation; C-H functionalization; Hydrocarbon oxidation; TERT-BUTYL HYDROPEROXIDE; MOLECULAR-OXYGEN; PERACETIC-ACID; ALDEHYDES; COMPLEXES; EFFICIENT; MANGANESE; ALKENES; CYTOCHROME-P-450; MONOOXYGENASE;

D O I：

10.1016/j.tetlet.2013.03.074

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-catalyzed oxidative functionalization of C-H bonds of alkanes with molecular oxygen has been performed in the presence of Cu(OAc)(2) catalyst and acetaldehyde in acetonitrile at 70 degrees C with extremely high turn-over numbers. (c) 2013 Elsevier Ltd. All rights reserved.

引用

页码：2706 / 2709

页数：4

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