Preparation of polymer/silica composite antiglare coatings on poly(ethylene terphathalate) (PET) substrates

被引：15

作者：

Chang, Chao-Ching ^{[1
,2
]}

Chen, Chien-Ming ^{[1
]}

Hwang, Feng-His ^{[1
]}

Chen, Ching-Chung ^{[2
]}

Cheng, Liao-Ping ^{[1
,2
]}

机构：

[1] Tamkang Univ, Dept Chem & Mat Engn, New Taipei City 25137, Taiwan

[2] Tamkang Univ, Energy & Optoelect Mat Res Ctr, New Taipei City 25137, Taiwan

来源：

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH | 2012年 / 9卷 / 05期

关键词：

Antiglare coating; Silica particle; Acrylate resin; UV-curing; Poly(ethylene terphathalate); Hardness; TRANSPARENT;

D O I：

10.1007/s11998-011-9392-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

3-(Trimethoxysilyl) propyl methacrylate and fluoroalkylsilane modified silica particles were UV-cured with the multifunctional crosslinking agent, dipentaerythritol hexaacrylate (DPHA), to prepare antiglare (AG) coatings that exhibit high hardness. Modified silica was used to impart surface roughness whereas DPHA was used to provide hardness and adhesiveness. The formed AG coatings were characterized in terms of topological, optical, and mechanical properties. It was found that with the increase of DPHA content in the coatings, the surface roughness and haze decreased while the gloss and clarity increased. For samples containing 40 and 50 wt% DPHA, the optical properties are comparable to commercial AG products for flat panel display and touch panels. These prepared coatings also demonstrate high hardness of 5-6H and 100% adhesion on poly(ethylene terphathalate) substrates.

引用

页码：561 / 568

页数：8

共 30 条

[1] Wet-chemical processing of transparent and antiglare conducting ITO coating on plastic substrates [J].

Aegerter, MA ;

Al-Dahoudi, N .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 27 (01) :81-89

[2] Transparent conducting, anti-static and anti-static-anti-glare coatings on plastic substrates [J].

Al-Dahoudi, N ;

Bisht, H ;

Göbbert, C ;

Krajewski, T ;

Aegerter, MA .

THIN SOLID FILMS, 2001, 392 (02) :299-304

[3] Preparation of polymer/silica hybrid hard coatings with enhanced hydrophobicity on plastic substrates [J].

Chang, Chao-Ching ;

Oyang, Tai-Yueh ;

Hwang, Feng-Hsi ;

Chen, Ching-Chung ;

Cheng, Liao-Ping .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (01) :72-76

[4] Preparation of organic-inorganic nano-composites for antireflection coatings [J].

Chen, Ching-Chung ;

Lin, Dar-Jong ;

Don, Trong-Min ;

Huang, Feng-Hsi ;

Cheng, Liao-Ping .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (32) :3828-3835

[5]

Chien J.-C., 2005, U.S. Patent, Patent No. [6,852,376 B2, 6852376]

[6] Preparation of almost dispersant-free colloidal silica with superb dispersiblility in organic solvents and monomers [J].

Huang, Feng-Hsi ;

Chang, Chao-Ching ;

Oyang, Tai-Yueh ;

Chen, Ching-Chung ;

Cheng, Liao-Ping .

JOURNAL OF NANOPARTICLE RESEARCH, 2011, 13 (09) :3885-3897

[7]

Kawahara S., 2005, US pat., Patent No. 6970213

[8]

Kuwabara M, 2007, US Patent, Patent No. [7,258,908, 7258908]

[9] Preparation and properties of nano-silica modified negative acrylate photoresist [J].

Lee, Chih-Kang ;

Don, Trong-Ming ;

Lai, Wei-Chi ;

Chen, Chin-Chung ;

Lin, Dar-Jong ;

Cheng, Liao-Ping .

THIN SOLID FILMS, 2008, 516 (23) :8399-8407

[10] Preparation of a nanosilica-modified negative-type acrylate photoresist [J].

Lin, Dar-Jong ;

Don, Trong-Ming ;

Chen, Chin-Chung ;

Lin, Bing-Yi ;

Lee, Chih-Kang ;

Cheng, Liao-Ping .

JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (02) :1179-1188

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