Redox-Regulated Rotary Motion of a Bis(9-triptycyl)-TTFV System

被引：23

作者：

Chen, Guang ^{[1
]}

Zhao, Yuming ^{[1
]}

机构：

[1] Mem Univ, Dept Chem, St John, NF A1B 3X7, Canada

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

MOLECULAR ROTORS; TETRATHIAFULVALENE VINYLOGUES; DYNAMIC STEREOCHEMISTRY; ROTATION; GEAR; TTF; STATORS; SURFACE; MOTOR;

D O I：

10.1021/ol403295q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A tetrathiafulvalene vinylogue (TTFV) unit was covalently linked to two benzyltriptycene molecular rotors to form a molecular gearset. Dynamic NMR studies showed that reversible redox reactions at the TTFV central unit exerted regulation over the rotational properties of the 9-triptycyl rotors.

引用

收藏

页码：668 / 671

页数：4

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