Palladium(II)-Catalyzed Direct Conversion of Methyl Arenes into Aromatic Nitriles

被引：134

作者：

Shu, Zhibin ^{[1
,2
]}

Ye, Yuxuan ^{[1
,2
]}

Deng, Yifan ^{[1
,2
]}

Zhang, Yan ^{[1
,2
]}

Wang, Jianbo ^{[1
,2
,3
]}

机构：

[1] Peking Univ, BNLMS, Coll Chem, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期

关键词：

ammoxidation; aromatic nitriles; homogeneous catalysis; methyl arenes; palladium; PALLADIUM-CATALYZED CYANATION; PRIMARY AMIDES; ARYL BROMIDES; ROBUST METHOD; AMMOXIDATION; ALDOXIMES; EFFICIENT; TRANSFORMATION; DEHYDRATION; OXIDATION;

D O I：

10.1002/anie.201305731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From methyl to nitrile: A mild ammoxidation method, which directly converts methyl arenes into aromatic nitriles, has been developed by using Pd(OAc) 2 and N-hydroxyphthalimide (NHPI) as the catalysts, and tert-butyl nitrite as the nitrogen source and oxidant. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10573 / 10576

页数：4

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