Low-cost birnessite as a promising cathode for high-performance aqueous rechargeable batteries

被引：118
作者：
Qiu, Nan [1 ]
Chen, Hong [1 ]
Yang, Zhaoming [1 ]
Sun, Sen [1 ]
Wang, Yuan [1 ]
机构：
[1] Sichuan Univ, Inst Nucl Sci & Technol, Minist Educ, Key Lab Radiat Phys & Technol, Chengdu 610064, Sichuan, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2018年 / 272卷
基金：
中国国家自然科学基金;
关键词：
Birnessite; Manganese oxide; Aqueous rechargeable batteries; Zinc; Cathode; ION BATTERY; HIGH-CAPACITY; ENERGY-STORAGE; CRYSTAL WATER; ZINC-STORAGE; LI; CHEMISTRY; ALPHA-MNO2; NICKEL; MNO2;
D O I：
10.1016/j.electacta.2018.04.012
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A highly reversible aqueous rechargeable battery system is assembled by using a Zn anode, a room-temperature synthesized MnO2-birnessite cathode and a mild ZnSO4-based aqueous electrolyte with MnSO4 as an additive. Structural analysis reveal that MnO2-birnessite undergoes a structural transformation to poorly crystalline MnO2. It offers an operating voltage of 1.39 V, an energy density of 364 Wh kg(-1) (cathode only) at 200 mA g(-1) and shows a capacity retention of 100% over 400 cycles at 500 mA g(-1). This low-cost battery system is a promising candidate for large-scale energy storage. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：154 / 160
页数：7
相关论文
共 46 条
[1]   Electrochemically Induced Structural Transformation in a γ-MnO2 Cathode of a High Capacity Zinc-Ion Battery System [J].
Alfaruqi, Muhammad H. ;
Mathew, Vinod ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Baboo, Joseph P. ;
Choi, Sun H. ;
Kim, Jaekook .
CHEMISTRY OF MATERIALS, 2015, 27 (10) :3609-3620
[2]   A layered δ-MnO2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications [J].
Alfaruqi, Muhammad Hilmy ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Duong Tung Pham ;
Jo, Jeonggeun ;
Xiu, Zhiliang ;
Mathew, Vinod ;
Kim, Jaekook .
ELECTROCHEMISTRY COMMUNICATIONS, 2015, 60 :121-125
[3]   Enhanced reversible divalent zinc storage in a structurally stable α-MnO2 nanorod electrode [J].
Alfaruqi, Muhammad Hilmy ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Jo, Jeonggeun ;
Kim, Seokhun ;
Mathew, Vinod ;
Kim, Jaekook .
JOURNAL OF POWER SOURCES, 2015, 288 :320-327
[4]   Electrodeposition of Sea Urchin and Cauliflower-like Nickel-/Cobalt-Doped Manganese Dioxide Hierarchical Nanostructures with Improved Energy-Storage Behavior [J].
Biswal, Avijit ;
Minakshi, Manickam ;
Tripathy, Bankim Chandra .
CHEMELECTROCHEM, 2016, 3 (06) :976-985
[5]   Evaluation of Effects of Additives in Wound Li-Ion Cells Through High Precision Coulometry [J].
Burns, J. C. ;
Jain, Gaurav ;
Smith, A. J. ;
Eberman, K. W. ;
Scott, Erik ;
Gardner, J. P. ;
Dahn, J. R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (03) :A255-A261
[6]   New-concept Batteries Based on Aqueous Li+/Na+ Mixed-ion Electrolytes [J].
Chen, Liang ;
Gu, Qingwen ;
Zhou, Xufeng ;
Lee, Saixi ;
Xia, Yonggao ;
Liu, Zhaoping .
SCIENTIFIC REPORTS, 2013, 3
[7]   Pomegranate-Structured Conversion-Reaction Cathode with a Built-in Li Source for High-Energy Li-Ion Batteries [J].
Fan, Xiulin ;
Zhu, Yujie ;
Luo, Chao ;
Suo, Liumin ;
Lin, Yan ;
Gao, Tao ;
Xu, Kang ;
Wang, Chunsheng .
ACS NANO, 2016, 10 (05) :5567-5577
[8]   An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3 [J].
Gao, Hongcai ;
Goodenough, John B. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (41) :12768-12772
[9]   Layered VS2 Nanosheet-Based Aqueous Zn Ion Battery Cathode [J].
He, Pan ;
Yan, Mengyu ;
Zhang, Guobin ;
Sun, Ruimin ;
Chen, Lineng ;
An, Qinyou ;
Mai, Liqiang .
ADVANCED ENERGY MATERIALS, 2017, 7 (11)
[10]   An aqueous rechargeable sodium ion battery based on a NaMnO2-NaTi2(PO4)3 hybrid system for stationary energy storage [J].
Hou, Zhiguo ;
Li, Xiaona ;
Liang, Jianwen ;
Zhu, Youngchun ;
Qian, Yitai .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (04) :1400-1404
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