Characterization and Photoluminescence Properties of Eu3+ Doped 3CdO-Al2O3-8SiO2 Amorphous System for White Light-Emitting Diodes

被引:11
作者
Cong, Yan [1 ,2 ]
Li, Bin [1 ,2 ]
Yue, Shumei [1 ,2 ]
Liu, Yanhong [1 ,2 ]
Li, Wenlian [1 ,2 ]
Wang, Xiao-jun [3 ]
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Georgia So Univ, Dept Phys, Statesboro, GA 30460 USA
关键词
NITRIDE; GREEN; BLUE; RED;
D O I
10.1021/jp8084414
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new phosphor, Eu3+ doped 3CdO-Al2O3-3SiO(2) (CAS:Eu3+), is prepared by a convenient sol-gel method. Under excitation either into the L-5(6) state with 394 nm or the D-5(2) state with 464 nm., the phosphor gives a red emission at 610 nm originating from the D-5(0) -> F-7(2) transition of Eu3+. The luminescence properties compared with YAG:Ce3+ and Y2O3:Eu3+ are studied. The red emission of CAS:Eu3+ is about 3 times stronger than that of commercial Y2O3:Eu3+. The high color saturation (the chromaticity index is x = 0.6209, y = 0.3461) and the low thermal quenching effect make phosphor CAS:Eu3+ a promising candidate for the phosphor-converted white LEDs.
引用
收藏
页码:493 / 495
页数:3
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