Selective oxidation of alcohols with H2O2 catalyzed by long chain multi-SO3H functionalized heteropolyanion-based ionic liquids under solvent-free conditions

被引：39

作者：

Li, Xinzhong ^{[1
,2
]}

Cao, Rong ^{[1
]}

Lin, Qi ^{[2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Univ Minjiang, Fujian Prov Key Lab Green Funct Mat, Dept Chem & Chem Engn, Fuzhou, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 69卷

关键词：

Selective oxidation; Heteropolyacid; Alcohols; Ionic liquids; H2O2; AEROBIC OXIDATION; RECYCLABLE CATALYST; SECONDARY ALCOHOLS; HYDROGEN-PEROXIDE; EFFICIENT; HYBRID; SYSTEM; WATER; POLYOXOMETALATE; OXYGEN;

D O I：

10.1016/j.catcom.2015.05.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two novel long chain multi-SO3H functionalized heteropolyanion-based ionic liquids were prepared and characterized. They as homogeneous catalysts showed high catalytic activity in selective oxidation of alcohols with 35% aqueous hydrogen peroxide under solvent-free conditions without adding any phase transfer catalyst. Two ionic liquids can be recovered readily and reused five times without any significant loss in their catalytic activities. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：5 / 10

页数：6

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