SEI Growth and Depth Profiling on ZFO Electrodes by Soft X-Ray Absorption Spectroscopy

被引：36

作者：

Di Cicco, Andrea ^{[1
]}

Giglia, Angelo ^{[2
]}

Gunnella, Roberto ^{[1
]}

Koch, Stephan L. ^{[3
,4
]}

Mueller, Franziska ^{[3
,4
]}

Nobili, Francesco ^{[5
]}

Pasqualini, Marta ^{[5
]}

Passerini, Stefano ^{[3
,4
]}

Tossici, Roberto ^{[5
]}

Witkowska, Agnieszka ^{[6
]}

机构：

[1] Univ Camerino, Sch Sci & Technol, Div Phys, I-62032 Camerino, MC, Italy

[2] CNR, Ist Officina Mat, I-34149 Trieste, Italy

[3] Helmholtz Inst Ulm, D-89081 Ulm, Germany

[4] Karlsruhe Inst Technol, D-76021 Karlsruhe, Germany

[5] Univ Camerino, Sch Sci & Technol, Div Chem, I-62032 Camerino, MC, Italy

[6] Gdansk Univ Technol, Dept Solid State Phys, PL-80233 Gdansk, Poland

来源：

ADVANCED ENERGY MATERIALS | 2015年 / 5卷 / 18期

关键词：

Li-ion batteries; solid electrolyte interface (SEI); X-ray absorption spectroscopy (XAS); ZNFE2O4; NANOPARTICLES; PROBING DEPTH; LITHIUM; ANODE; BATTERIES; SPECTRA; CATHODE; YIELD; EDGE;

D O I：

10.1002/aenm.201500642

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The evolution of the solid electrolyte interface (SEI) in carbon-coated ZnFe2O4 (ZFO-C) anodes is studied by soft X-ray absorption spectroscopy (XAS). Experiments probe locally the SEI growth in the 2-100 nm range, using both total electron (TEY) and total fluorescence (TFY) yield techniques. XAS analysis shows that the SEI grows preferentially around the ZFO-C nanoparticles. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页数：6

共 19 条

[1] PROBING DEPTH OF SOFT-X-RAY ABSORPTION-SPECTROSCOPY MEASURED IN TOTAL-ELECTRON-YIELD MODE [J].

ABBATE, M ;

GOEDKOOP, JB ;

DEGROOT, FMF ;

GRIONI, M ;

FUGGLE, JC ;

HOFMANN, S ;

PETERSEN, H ;

SACCHI, M .

SURFACE AND INTERFACE ANALYSIS, 1992, 18 (01) :65-69

[2] Failure and stabilization mechanisms of graphite electrodes [J].

Aurbach, D ;

Levi, MD ;

Levi, E ;

Schechter, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (12) :2195-2206

[3] Lithium K(1s) synchrotron NEXAFS spectra of lithium-ion battery cathode, anode and electrolyte materials [J].

Braun, Artur ;

Wang, Hongxin ;

Shim, Joongpyo ;

Lee, Steven S. ;

Cairns, Elton J. .

JOURNAL OF POWER SOURCES, 2007, 170 (01) :173-178

[4] Transition-Metal-Doped Zinc Oxide Nanoparticles as a New Lithium-Ion Anode Material [J].

Bresser, Dominic ;

Mueller, Franziska ;

Fiedler, Martin ;

Krueger, Steffen ;

Kloepsch, Richard ;

Baither, Dietmar ;

Winter, Martin ;

Paillard, Elie ;

Passerini, Stefano .

CHEMISTRY OF MATERIALS, 2013, 25 (24) :4977-4985

[5] Carbon Coated ZnFe2O4 Nanoparticles for Advanced Lithium-Ion Anodes [J].

Bresser, Dominic ;

Paillard, Elie ;

Kloepsch, Richard ;

Krueger, Steffen ;

Fiedler, Martin ;

Schmitz, Rene ;

Baither, Dietmar ;

Winter, Martin ;

Passerini, Stefano .

ADVANCED ENERGY MATERIALS, 2013, 3 (04) :513-523

[6] SEI film formation on highly crystalline graphitic materials in lithium-ion batteries [J].

Buqa, H ;

Würsig, A ;

Vetter, J ;

Spahr, ME ;

Krumeich, F ;

Novák, P .

JOURNAL OF POWER SOURCES, 2006, 153 (02) :385-390

[7] The probing depth of total electron yield in the sub-keV range: TEY-XAS and X-PEEM [J].

Frazer, BH ;

Gilbert, B ;

Sonderegger, BR ;

De Stasio, G .

SURFACE SCIENCE, 2003, 537 (1-3) :161-167

[8] Review on recent progress of nanostructured anode materials for Li-ion batteries [J].

Goriparti, Subrahmanyam ;

Miele, Ermanno ;

De Angelis, Francesco ;

Di Fabrizio, Enzo ;

Zaccaria, Remo Proietti ;

Capiglia, Claudio .

JOURNAL OF POWER SOURCES, 2014, 257 :421-443

[9] Sampling depth of total electron and fluorescence measurements in Si L- and K-edge absorption spectroscopy [J].

Kasrai, M ;

Lennard, WN ;

Brunner, RW ;

Bancroft, GM ;

Bardwell, JA ;

Tan, KH .

APPLIED SURFACE SCIENCE, 1996, 99 (04) :303-312

[10] Comparing anode and cathode electrode/electrolyte interface composition and morphology using soft and hard X-ray photoelectron spectroscopy [J].

Malmgren, S. ;

Ciosek, K. ;

Hahlin, M. ;

Gustafsson, T. ;

Gorgoi, M. ;

Rensmo, H. ;

Edstrom, K. .

ELECTROCHIMICA ACTA, 2013, 97 :23-32

← 1 2 →