Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles

被引：254

作者：

Ab Rahim, Mohd Hasbi ^{[1
]}

Forde, Michael M. ^{[1
]}

Jenkins, Robert L. ^{[1
]}

Hammond, Ceri ^{[1
]}

He, Qian ^{[2
]}

Dimitratos, Nikolaos ^{[1
]}

Lopez-Sanchez, Jose Antonio ^{[1
]}

Carley, Albert F. ^{[1
]}

Taylor, Stuart H. ^{[1
]}

Willock, David J. ^{[1
]}

Murphy, Damien M. ^{[1
]}

Kiely, Christopher J. ^{[2
]}

Hutchings, Graham J. ^{[1
]}

机构：

[1] Cardiff Univ, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales

[2] Lehigh Univ, Dept Mat Sci & Engn, Bethlehem, PA 18015 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 04期

关键词：

alloys; gold; methane; oxidation; palladium; DIRECT CONVERSION; CATALYTIC CONVERSION; LOW-TEMPERATURE; OXYGENATION; ACTIVATION;

D O I：

10.1002/anie.201207717

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct and selective: Supported gold-palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1280 / 1284

页数：5

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