Coordination chemistry of macrocyclic multidentate Lewis acids.: Synthesis and structures of complexes of cyclic trimeric perfluoro-o-phenylenemercury with N,N-dimethylacetamide and n-butyronitrile

被引：21
|
作者：
Tikhonova, IA
Dolgushin, FM
Tugashov, KI
Furin, GG
Petrovskii, PV
Shur, VB
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 09期
关键词：
polymercury-containing macrocycles; Lewis acids; carboxamides; nitrites; complexes; X-ray diffraction analysis;
D O I：
10.1023/A:1013059207407
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)(3) readily reacts with N,N-dimethylacetamide and n-butyronitrile to form the complexes {[(o-C6F4Hg)(3)](MeCONMe2)(2)} and {[o-C6F4Hg)(3)]((PrCN)-C-n)} respectively. According to X-ray diffraction data, the amide ligands are located above and below the plane of the macrocycle, each being coordinated to all Hg atoms of the macrocycle through the O atom. The nitrite ligand is bound to the macrocycle through the N atom, all Hg atoms being also involved in this bonding.
引用
收藏
页码：1673 / 1678
页数：6
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