The Chemistry of CO: Carbonylation

被引：495
作者：
Peng, Jin-Bao [1 ]
Geng, Hui-Qing [1 ]
Wu, Xiao-Feng [1 ,2 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China
[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
CHEM | 2019年 / 5卷 / 03期
基金：
中国国家自然科学基金;
关键词：
CARBON-MONOXIDE REACTIONS; ANION TRAPPING REACTIONS; METAL-FREE; CATALYZED CARBONYLATION; KOCH CARBONYLATION; ALKYL IODIDES; ORGANOMETALLIC COMPOUNDS; RADICAL CARBONYLATION; SELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS;
D O I：
10.1016/j.chempr.2018.11.006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbon monoxide is one of the most important C1 molecules in organic chemistry. Many novel procedures for its conversion have been developed, and some have even been industrialized. In this review, we discuss and categorize CO chemistry into four classes: (1) transition-metal-mediated carbonylation, (2) strong-acid-initiated cationic carbonylation, (3) anionic carbonylation, and (4) free-radical carbonylation. Relevant achievements are selected and discussed in detail.
引用
收藏
页码：526 / 552
页数：27
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