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Densities and volumetric properties of 2-chloroethanol with N,N-dimethylformamide and water at different temperatures
被引:20
作者:
Xu, L
[1
]
Lin, GM
[1
]
Wang, X
[1
]
Lin, RS
[1
]
机构:
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
基金:
中国国家自然科学基金;
关键词:
densities;
excess molar volumes;
2-chloroethanol;
N;
N-dimethylformamide;
(DMF);
water;
D O I:
10.1016/j.molliq.2005.06.004
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Densities of binary mixtures of 2-chloroethanol with N,N-dimethylformamide (DMF) and water have been measured over the full range of compositions at various temperatures. From these results, excess molar volumes, V-E and excess partial molar volumes at infinite dilution, (V) over bar (E,0)(i) have been calculated. V-E for (DMF + 2-chloroethanol) mixture are positive over the whole mole fraction range and negative values are obtained for (water+ 2-chloroethanol) mixture. (C) 2005 Elsevier B.V. All rights reserved.
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页码:130 / 133
页数:4
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