Rh-catalyzed linear hydroformylation of styrene

被引：36

作者：

Boymans, Evert ^{[1
]}

Janssen, Michele ^{[1
]}

Mueller, Christian ^{[1
,2
]}

Lutz, Martin ^{[3
]}

Vogt, Dieter ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Schuit Inst Catalysis, Lab Homogeneous Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

[3] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 01期

关键词：

HIGHLY REGIOSELECTIVE HYDROFORMYLATION; LIGANDS; HYDROCYANATION; PRESSURE; 1,3-CYCLOHEXADIENE;

D O I：

10.1039/c2dt31738a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong pi-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed hydroformylation of styrene. High selectivities up to 83% of 3-phenylpropanal were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite) with virtually no hydrogenation to ethyl benzene. The coordination chemistry of those ligands towards Rh(I) was investigated spectroscopically and structurally.

引用

页码：137 / 142

页数：6

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