Control of rotor motion in a light-driven molecular motor: Towards a molecular gearbox

被引:37
作者
ter Wiel, MKJ [1 ]
van Delden, RA [1 ]
Meetsma, A [1 ]
Feringa, BL [1 ]
机构
[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, Stratingh Inst, NL-9747 AG Groningen, Netherlands
关键词
D O I
10.1039/b510641a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Controlled intramolecular movement and coupling of motor and rotor functions is exerted by this new molecular device. The rate of rotation of the rotor part of the molecule can be adjusted by alteration of the conformation of the motor part of the molecule. For all states of the motor part, different rates of rotation were measured for the rotor part. Conversion between the four propeller orientations was achieved by irradiation and heating.
引用
收藏
页码:4071 / 4076
页数:6
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