ELECTRODEGRADATION OF PONCEAU 2R USING DIMENSIONALLY-STABLE ANODES AND Ti/Pt

被引:9
作者
Paulino Ribeiro, Francisco Wirley [1 ]
Oliveira, Sameque do Nascimento [1 ]
de Lima-Neto, Pedro [1 ]
Correia, Adriana Nunes [1 ]
Mascaro, Lucia Helena [2 ]
de Matos, Roberto [2 ]
Pereira de Souza, Ernesto Chaves [2 ]
de Vasconcelos Lanza, Marcos Roberto [3 ]
机构
[1] Univ Fed Ceara, Ctr Ciencias, Dept Quim Analit & Fis Quim, Campus Pici, BR-60455970 Fortaleza, CE, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil
[3] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源
QUIMICA NOVA | 2013年 / 36卷 / 01期
关键词
Ponceau; 2R; DSA; Ti/Pt; ELECTROCHEMICAL DEGRADATION; WASTE-WATER; XYLIDINE PONCEAU; OXIDATION; DECOLORIZATION; PERFORMANCE; DIAMOND; DECOLORATION; POLLUTANTS; ORGANICS;
D O I
10.1590/S0100-40422013000100016
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ELECTRODEGRADATION OF PONCEAU 2R USING DIMENSIONALLY-STABLE ANODES AND Ti/Pt. This paper reports the electrochemical degradation of the azo dye Ponceau 2R under galvanostatic electrolysis in the 1 to 200 mA cm(-2) range at room temperature using dimensionally-stable anodes of oxygen (DSA-O-2), chlorine (DSA-Cl-2) and a titanium electrode of platinum coated with platinum oxide (Ti/Pt). The methodology applied was efficient for removing the color of the Ponceau 2R and the highest percentage removal of total organic carbon was obtained at 200 mA cm(-2). Despite not having been observed complete mineralization, approximately80% removal of aromatic rings was estimated, resulting in drastic reduction of toxicity of the sample.
引用
收藏
页码:85 / 90
页数:6
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