Effect of anionic surfactant sodium dodecyl sulfate on the reaction of hexacyanoferrate(III) oxidation of levothyroxine in aqueous medium: a kinetic and mechanistic approach

被引：5

作者：

Khan, Aftab Aslam Parwaz ^{[1
,2
]}

Asiri, Abdullah M. ^{[1
,2
]}

Khan, Anish ^{[1
,2
]}

Azum, Naved ^{[1
,2
]}

Rub, Malik Abdul ^{[1
]}

Rahman, Mohammed M. ^{[1
,2
]}

Khan, Sher Bahadar ^{[1
,2
]}

机构：

[1] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

[2] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21589, Saudi Arabia

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2013年 / 39卷 / 06期

关键词：

Levothyroxine; Kinetics; SDS; CMC; DEGRADATION-PRODUCTS; THYROXINE HORMONE; ELECTRON-TRANSFER; MICELLAR; IMMUNOASSAY; ACID;

D O I：

10.1007/s11164-012-0764-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of anionic surfactant sodium dodecyl sulfate (SDS) on the rate of oxidation of levothyroxine (LVT) by hexacyanoferrate(III) in alkaline medium has been investigated spectrophotometrically at different temperatures. The reaction follows a complex kinetics showing first order dependence of rate with respect to both alkali and LVT. The effect of SDS on the rate of reaction has been observed at the critical miceller concentration of the surfactant. indicating binding of the substrate with the surfactant micelle. The binding parameters have also been evaluated using the Menger and Portnoy model.

引用

页码：2379 / 2389

页数：11

共 29 条

[21] LONG-TERM L-THYROXINE THERAPY IS ASSOCIATED WITH DECREASED HIP BONE-DENSITY IN PREMENOPAUSAL WOMEN [J].

PAUL, TL ;

KERRIGAN, J ;

KELLY, AM ;

BRAVERMAN, LE ;

BARAN, DT .

JAMA-JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION, 1988, 259 (21) :3137-3141

[22] Mechanistic investigations of the oxidation of substituted phenethyl alcohols by manganese(III) sulfate catalyzed by ruthenium(III) in acid solution [J].

Rangappa, KS ;

Anitha, N ;

Gowda, NMM .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2001, 31 (08) :1499-1518

[23] Immunoassay for thyroxine (T4) in serum using capillary electrophoresis and micromachined devices [J].

Schmalzing, D ;

Koutny, LB ;

Taylor, TA ;

Nashabeh, W ;

Fuchs, M .

JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 1997, 697 (1-2) :175-180

[24]

Sherwani MRK, 2003, INDIAN J CHEM A, V42, P2527

[25] Determination of thyroxine in the hair of newborns by radioimmunoassay with high-performance liquid chromatographic confirmation [J].

Tagliaro, F ;

Camilot, M ;

Valentini, R ;

Mengarda, F ;

Antoniazzi, F ;

Tatò, L .

JOURNAL OF CHROMATOGRAPHY B, 1998, 716 (1-2) :77-82

[26]

Taimela E, 1997, EUR J CLIN CHEM CLIN, V35, P889

[27] Flow-injection chemiluminometric analysis of thyroxine hormone in a KMnO4-Na2SO3 system [J].

Waseem, Amir ;

Yaqoob, Mohammad ;

Nabi, Abdul .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2007, 54 (06) :1505-1510

[28]

Weissberger A., 1974, TECHNIQUES CHEM, V4, P421

[29]

WORTSMAN J, 1989, CLIN CHEM, V35, P90

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