Synthesis, characterization and application of red-emitting CuInS2/ZnS quantum dots for warm white light-emitting diodes

被引：26
作者：
Dong, Xuan [1 ]
Ren, Jiejun [1 ]
Li, Tianrong [2 ]
Wang, Yuhua [1 ]
机构：
[1] Lanzhou Univ, Key Lab Special Funct Mat & Struct Design,Dept Ma, Sch Phys Sci & Technol,Natl Dev & Reform Commiss, Minist Educ,Natl & Local Joint Engn Lab Opt Conve, Lanzhou 730000, Gansu, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China
来源：
DYES AND PIGMENTS | 2019年 / 165卷
关键词：
Quantum dots; CuInS2; YAG:Ce; White LED; Optical materials; OPTICAL-PROPERTIES; THERMAL-STABILITY; FACILE SYNTHESIS; ENERGY-TRANSFER; LUMINESCENCE; NANOCRYSTALS; EMISSION; PHOSPHOR; DYNAMICS; NANOPARTICLES;
D O I：
10.1016/j.dyepig.2019.02.035
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Ce-doped yttrium aluminum garnet (YAG:Ce) is an important phosphor in the phosphor-converted white light emitting diode (WLED) while YAG:Ce-based WLED is cold and blue so that impair the performance of WLED. In order to achieve warm WLED, in this study, CuInS2/ZnS colloidal quantum dots (CIS/ZnS QDs) has been designed and synthesized. The crystal structure, photoluminescence and thermoluminescence have been measured and analyzed. The lighting film was realized by adding CIS/ZnS QDs into YAG:Ce-silicone, fabricating with InGaN-based blue LED to display warm white light which Commission International de L'Eclairage chromaticity coordinates at (0.3814, 0.3237) and correlated color temperature of 3415K. Our experiments show that film consists of YAG:Ce and red-emitting CIS/ZnS QDs is able to achieve warm WLED with desired results.
引用
收藏
页码：273 / 278
页数：6
相关论文
共 52 条
[1]   Ce-Doped YAG Nanophosphor and Red Emitting CuInS2/ZnS Core/Shell Quantum Dots for Warm White Light-Emitting Diode with High Color Rendering Index [J].
Aboulaich, Abdelhay ;
Michalska, Martyna ;
Schneider, Raphael ;
Potdevin, Audrey ;
Deschamps, Jerome ;
Deloncle, Rodolphe ;
Chadeyron, Genevieve ;
Mahiou, Rachid .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (01) :252-258
[2]   One-Pot Aqueous Synthesis of Highly Biocompatible Near Infrared CuInS2 Quantum Dots for Target Cell Imaging [J].
Arshad, Anila ;
Chen, Hongli ;
Bai, Xilin ;
Xu, Suying ;
Wang, Leyu .
CHINESE JOURNAL OF CHEMISTRY, 2016, 34 (06) :576-582
[3]   Color Point Tuning for (Sr,Ca,Ba)Si2O2N2:Eu2+ for White Light LEDs [J].
Bachmann, Volker ;
Ronda, Cees ;
Oeckler, Oliver ;
Schnick, Wolfgang ;
Meijerink, Andries .
CHEMISTRY OF MATERIALS, 2009, 21 (02) :316-325
[4]   Radiative and Nonradiative Recombination in CuInS2 Nanocrystals and CuInS2-Based Core/Shell Nanocrystals [J].
Berends, Anne C. ;
Rabouw, Freddy T. ;
Spoor, Frank C. M. ;
Bladt, Eva ;
Grozema, Ferdinand C. ;
Houtepen, Arjan J. ;
Siebbeles, Laurens D. A. ;
Donega, Celso de Mello .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (17) :3503-3509
[5]   Direct Identification of Surface Defects and Their Influence on the Optical Characteristics of Upconversion Nanoparticles [J].
Bian, Wenjuan ;
Lin, Yue ;
Wang, Ting ;
Yu, Xue ;
Qiu, Jianbei ;
Zhou, Meng ;
Luo, Hongmei ;
Yu, Siu Fung ;
Xu, Xuhui .
ACS NANO, 2018, 12 (04) :3623-3628
[6]   Ultrafast charge dynamics in CuInS2 nanocrystal quantum dots [J].
Cadirci, Musa ;
Masala, Ombretta ;
Pickett, Nigel ;
Binks, David .
CHEMICAL PHYSICS, 2014, 438 :60-65
[7]   Synthesis and characterization of colloidal CuInS2 nanoparticles from a molecular single-source precursor [J].
Castro, SL ;
Bailey, SG ;
Raffaelle, RP ;
Banger, KK ;
Hepp, AF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (33) :12429-12435
[8]   Highly Emissive and Color-Tunable CuInS2-Based Colloidal Semiconductor Nanocrystals: Off-Stoichiometry Effects and Improved Electroluminescence Performance [J].
Chen, Bingkun ;
Zhong, Haizheng ;
Zhang, Wenqing ;
Tan, Zhan'ao ;
Li, Yongfang ;
Yu, Cairan ;
Zhai, Tianyou ;
Bando, Yoshio ;
Yang, Shengyi ;
Zou, Bingsuo .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (10) :2081-2088
[9]   Subpicosecond Exciton Dynamics and Biexcitonic Feature in Colloidal CuInS2 Nanocrystals: Role of In-Cu Antisite Defects [J].
Debnath, Tushar ;
Maiti, Sourav ;
Maity, Partha ;
Ghosh, Hirendra N. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (17) :3458-3465
[10]   High-Quality CuInS2/ZnS Quantum Dots for In vitro and In vivo Bioimaging [J].
Deng, Dawei ;
Chen, Yuqi ;
Cao, Jie ;
Tian, Junmei ;
Qian, Zhiyu ;
Achilefu, Samuel ;
Gu, Yueqing .
CHEMISTRY OF MATERIALS, 2012, 24 (15) :3029-3037
123456