Design of an Active Site towards Optimal Electrocatalysis: Overlayers, Surface Alloys and Near-Surface Alloys of Cu/Pt(111)

被引：101

作者：

Bandarenka, Aliaksandr S. ^{[1
]}

Varela, Ana Sofia ^{[1
]}

Karamad, Mohammedreza ^{[2
]}

Calle-Vallejo, Federico ^{[2
]}

Bech, Lone ^{[1
]}

Perez-Alonso, Francisco J. ^{[1
]}

Rossmeisl, Jan ^{[2
]}

Stephens, Ifan E. L. ^{[1
]}

Chorkendorff, Ib ^{[1
]}

机构：

[1] Tech Univ Denmark, Ctr Individual Nanoparticle Funct, DK-2800 Lyngby, Denmark

[2] Tech Univ Denmark, Ctr Atom Scale Mat Design, DK-2800 Lyngby, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 47期

基金：

新加坡国家研究基金会;

关键词：

Cu/Pt alloy; cyclic voltammetry; density functional calculations; electrocatalysis; electrochemistry; OXYGEN REDUCTION REACTION; CATALYTIC-ACTIVITY; CO; PLATINUM; ADSORPTION; OXIDATION; HYDROGEN; PT(111); TRENDS; ELECTROREDUCTION;

D O I：

10.1002/anie.201205314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

I could never be without Cu: An active site has been designed for the catalysis of CO electroxidation. This was achieved by incorporating submonolayer amounts of Cu (orange spheres) into a single crystal of Pt (gray spheres). The electrochemical reactivity of this surface was highly sensitive to the exact position of Cu (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11845 / 11848

页数：4

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