Physico-chemical properties of the C70-L-lysine aqueous solutions

被引:17
|
作者
Serebryakov, Evgeny B. [1 ]
Semenov, Konstantin N. [1 ]
Stepanyuk, Irina V. [2 ]
Charykov, Nikolay A. [2 ]
Mescheryakov, Anatolii N. [1 ]
Zhukov, Anatolii N. [1 ]
Chaplygin, Alexey V. [3 ]
Murin, Igor V. [1 ]
机构
[1] St Petersburg State Univ, Univ Skii Pr 26, St Petersburg 198504, Russia
[2] St Petersburg State Technol Inst Tech Univ, Moskovskii Pr 26, St Petersburg 190013, Russia
[3] North Western State Med Univ, Piskarevskij Pr 47, St Petersburg 195067, Russia
基金
俄罗斯基础研究基金会;
关键词
Fullerene; L-Lysine; Refractometry; Specific conductivity; Molar conductivity; Dissociation constant; Excess thermodynamic functions; Viscosity; SOLUBLE AMINO-ACID; PEPTIDE DERIVATIVES; WATER; FULLERENE; ASSOCIATION; DEPENDENCE; C-60;
D O I
10.1016/j.molliq.2018.02.057
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The paper is devoted to investigation of physico-chemical properties of the C-70-L-lysine derivative aqueous solutions. Within the framework of our investigation, we have studied the concentration dependences of density, average molar volume and partial molar volumes of the solution components, specific and molar conductivities, dissociation constant, apparent degree of dissociation,-potential as well as concentration dependences of the C-70-L-lysine associates size distribution in aqueous solutions. Additionally we have used the semi-empirical VD-AS (Virial Decomposition Asymmetric Model) model and calculated the excess thermodynamic functions of solutions and solution components. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:507 / 518
页数:12
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