Electrocatalytic layers modified by reduced graphene oxide for PEM fuel cells

被引：40
作者：
Pushkarev, A. S. [1 ]
Pushkareva, I. V. [1 ]
Grigoriev, S. A. [2 ]
Kalinichenko, V. N. [3 ]
Presniakov, M. Yu. [1 ]
Fateev, V. N. [1 ]
机构：
[1] Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia
[2] Natl Res Univ, Moscow Power Engn Inst, Moscow 111250, Russia
[3] DELTARUS Ltd, Dolgoprudnyi 141700, Moscow Region, Russia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 42期
基金：
俄罗斯基础研究基金会; 俄罗斯科学基金会;
关键词：
Reduced graphene oxide; Fuel cell; Proton-exchange membrane; Electrocatalytic layer; Magnetron-ion sputtering; CARBON; CATALYSTS; PLATINUM;
D O I：
10.1016/j.ijhydene.2015.05.093
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reduced graphene oxide (RGO) with specific surface area of ca. 600 m(2)/g was synthesized and characterized. A series of membrane-electrode assemblies with RGO addition (in amount from 0 to 6 wt%) to electrocatalytic composition based on 40 wt% of Pt on Vulcan XC-72 were fabricated and tested. Pt/Vulcan XC-72 was synthesized using magnetron-ion sputtering in an impulse mode. It was shown that the optimum content of RGO in the fuel cell active layer is ca. 1 wt%. In particular, at this RGO concentration the maximum fuel cell power density is increased by ca. 8.5% in comparison with no-RGO containing electrocatalytic layers. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：14492 / 14497
页数：6
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