Synthesis, Structure, and Catalytic Epoxidation Property of a New Phenolato and μ1,1,3-Azido Co-Bridged Polynuclear Manganese(III) Complex Derived from N,N′-Bis(5-methylsalicylidene)ethane-1,2-diamine

被引：1
|
作者：
Wang, Ning [1 ]
机构：
[1] Henan Univ Urban Construct, Dept Chem Engn, Pingdingshan 467044, Peoples R China
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2015年 / 68卷 / 09期
关键词：
SCHIFF-BASE COMPLEXES; LIGANDS; OXIDATION; POLYMERS; MN(II); CHAIN;
D O I：
10.1071/CH15068
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new phenolato and mu(1,1,3)-azido co-bridged polynuclear manganese(III) complex has been synthesised and characterised. The structure of the complex has been confirmed by single crystal X-ray diffraction analyses. The ability of the complex to catalyse the epoxidation of styrene using PhIO or NaOCl as oxidant has been studied. Results show the catalysis to occur efficiently in the presence of PhIO and NaOCl.
引用
收藏
页码：1434 / 1437
页数：4
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