Graphene-supported Au-Pd bimetallic nanoparticles with excellent catalytic performance in selective oxidation of methanol to methyl formate

被引：128

作者：

Wang, Ruiyi ^{[1
,2
]}

Wu, Zhiwei ^{[1
]}

Chen, Chengmeng ^{[3
]}

Qin, Zhangfeng ^{[1
]}

Zhu, Huaqing ^{[1
]}

Wang, Guofu ^{[1
]}

Wang, Hao ^{[1
]}

Wu, Chengming ^{[1
,2
]}

Dong, Weiwen ^{[1
,2
]}

Fan, Weibin ^{[1
]}

Wang, Jianguo ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, POB 165, Taiyuan 030001, Shanxi, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Shanxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期

关键词：

SOLVENT-FREE OXIDATION; GOLD CATALYSTS; HYDROGEN; NANOSHEETS; MECHANISM;

D O I：

10.1039/c3cc43948h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Graphene supported Au-Pd bimetallic nanoparticles exhibit high catalytic activity in methanol selective oxidation, with a methanol conversion of 90.2% and selectivity of 100%, to methyl formate at 70 degrees C, owing to the synergism of Au and Pd particles as well as the strong interaction between graphene and Au-Pd nanoparticles.

引用

页码：8250 / 8252

页数：3

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