Chemicals from ethanol-The acetone one-pot synthesis

被引：52
作者：
Rodrigues, Clarissa P. [1 ]
Zonetti, Priscila C. [1 ]
Silva, Camila G. [1 ]
Gaspar, Alexandre B. [1 ]
Appel, Lucia G. [1 ]
机构：
[1] Inst Nacl Tecnol, Div Catalise & Proc Quim, BR-21081312 Rio De Janeiro, RJ, Brazil
来源：
APPLIED CATALYSIS A-GENERAL | 2013年 / 458卷
关键词：
Acetone; Ethanol; Zirconia; Ketonization; IN-SITU DRIFT; ACETALDEHYDE ADSORPTION; OXIDE CATALYST; ACETIC-ACID; CONVERSION; ZIRCONIA; METHANOL; KETONIZATION; CHEMISTRY;
D O I：
10.1016/j.apcata.2013.03.028
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ethanol is a platform molecule that can generate many different products employing one-pot processes and multifunctional catalysts. The synthesis of acetone from ethanol is a good example of these processes. Some authors studied the generation of acetone from ethanol and proposed mechanisms which are not fully in agreement. This work using catalyst physical mixtures and IR spectroscopy (DRIFTS) is consistent with the generation of acetone from ethanol by ketonization of carboxylates which are obtained by dehydrogenation of this alcohol followed by oxidation. These results confirm that physical mixtures of catalysts can be a valuable tool in order to study the mechanism of multi-step reactions. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：111 / 118
页数：8
相关论文
共 50 条
  • [31] One-pot synthesis of α-acyloxycarboxamidobarbiturates from alloxans, carboxylic acids, and isocyanides
    Teimouri, Mohammad Bagher
    [J]. JOURNAL OF CHEMICAL RESEARCH, 2012, (07) : 432 - 436
  • [32] One-Pot Synthesis of N-Iodo Sulfoximines from Sulfides
    Zupanc, Anze
    Jereb, Marjan
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (08) : 5991 - 6000
  • [33] ONE-POT SYNTHESIS OF α-MONOSUBSTITUTED PYRIDINIUMS FROM CORRESPONDING PYRYLIUM SALTS
    Li, Gang
    Gong, Wei-Tao
    Ye, Jun-Wei
    Lin, Yuan
    Ning, Gui-Ling
    [J]. SYNTHETIC COMMUNICATIONS, 2012, 42 (04) : 480 - 486
  • [34] One-pot synthesis of sulfur heterocycles from simple organic substrates
    Rakitin, Oleg A.
    [J]. ARKIVOC, 2009, : 129 - 149
  • [35] One-pot synthesis of isosorbide from cellulose or lignocellulosic biomass: a challenge?
    Bonnin, Isaline
    Mereau, Raphael
    Tassaing, Thierry
    Vigier, Karine De Oliveira
    [J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2020, 16 : 1713 - 1721
  • [36] One pot synthesis of N-ethylaniline from nitrobenzene and ethanol
    XiaoNian Li
    JunHua Zhang
    YiZhi Xiang
    Lei Ma
    QunFeng Zhang
    ChunShan Lu
    Hong Wang
    Ying Bai
    [J]. Science in China Series B: Chemistry, 2008, 51 : 248 - 256
  • [37] Diacetoxyiodobenzene Mediated One-Pot Synthesis of Diverse Carboxamides from Aldehydes
    Prasad, Virendra
    Kale, Raju R.
    Mishra, Bhuwan B.
    Kumar, Dhananjay
    Tiwari, Vinod K.
    [J]. ORGANIC LETTERS, 2012, 14 (12) : 2936 - 2939
  • [38] One pot synthesis of N-ethylaniline from nitrobenzene and ethanol
    Li XiaoNian
    Zhang JunHua
    Xiang Yizhi
    Ma Lei
    Zhang QunFeng
    Lu ChunShan
    Wang Hong
    Bai Ying
    [J]. SCIENCE IN CHINA SERIES B-CHEMISTRY, 2008, 51 (03): : 248 - 256
  • [39] One pot synthesis of N-ethylaniline from nitrobenzene and ethanol
    LI XiaoNian
    [J]. Science in China(Series B:Chemistry), 2008, (03) : 248 - 256
  • [40] One-pot chemoenzymatic synthesis of aldoximes from primary alcohols in water
    Zambelli, Paolo
    Pinto, Andrea
    Romano, Diego
    Crotti, Elena
    Conti, Paola
    Tamborini, Lucia
    Villa, Raffaella
    Molinari, Francesco
    [J]. GREEN CHEMISTRY, 2012, 14 (08) : 2158 - 2161
12345