Plasma polymerized acetaldehyde thin films for retention of volatile organic compounds

被引:1
作者
Hernandez, Leonardo Frois [1 ]
Lima, Roberto da Rocha [2 ]
de Carvalho, Alexsander Tressino [3 ]
Demarquette, Nicole Raymonde [3 ]
Pereira da Silva, Maria Lucia [3 ]
机构
[1] Fac Tecnol Sao Paulo, BR-01124060 Sao Paulo, Brazil
[2] Univ Sao Paulo, Inst Fis, BR-05508090 Sao Paulo, Brazil
[3] Univ Sao Paulo, Escola Politecn, BR-05508090 Sao Paulo, Brazil
来源
QUIMICA NOVA | 2008年 / 31卷 / 06期
基金
巴西圣保罗研究基金会;
关键词
microcolumns for chromatography; plasma polymerization; adsorbent organic thin films;
D O I
10.1590/S0100-40422008000600025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aim of this work is the production and characterization of plasma polymerized acetaldehyde thin films. These films show highly polar species. are hydrophilic. organophilic and easily adsorb organic reactants with CO radicals but only allow permeation of reactants with OH radicals. The good step coverage of films deposited on aluminum trenches is useful for sensor development. Films deposited on hydrophobic Substrates may result in a discontinued layer, which allows the use of preconcentration in sample pretreatment. Deposition on microchannels showed the possibility of chromatographic columns and/or retention system production to selectively detect or remove organic compounds from gas flows.
引用
收藏
页码:1410 / 1416
页数:7
相关论文
共 31 条
[1]   Adsorption of ionic surfactants to a plasma polymer substrate [J].
Atkin, R ;
Craig, VSJ ;
Hartley, PG ;
Wanless, EJ ;
Biggs, S .
LANGMUIR, 2003, 19 (10) :4222-4227
[2]   Porous silicon as a sacrificial material [J].
Bell, TE ;
Gennissen, PTJ ;
DeMunter, D ;
Kuhl, M .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 1996, 6 (04) :361-369
[3]  
CARVALHO AT, 2006, MAT RES, V9, P9
[4]   Plasma polymerized TEOS films for nanochannels formation and sensor development [J].
Carvalho, RAM ;
Lima, RR ;
Nascimento, AP ;
Silva, MLP ;
Demarquette, NR .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2) :955-963
[5]  
Gong X., 1997, PLASMAS POLYM, V2, P261
[6]   Sorptive polymeric materials and photopatterned films for gas phase chemical microsensors [J].
Grate, JW ;
Nelson, DA .
PROCEEDINGS OF THE IEEE, 2003, 91 (06) :881-889
[7]   On-line membrane extraction liquid chromatography for monitoring semi-volatile organics in aqueous matrices [J].
Guo, XM ;
Mitra, S .
JOURNAL OF CHROMATOGRAPHY A, 2000, 904 (02) :189-196
[8]   In-situ chemiresistor sensor package for real-time detection of volatile organic compounds in soil and groundwater [J].
Ho, CK ;
Hughes, RC .
SENSORS, 2002, 2 (01) :23-34
[9]   In situ monitoring of vapor phase TCE using a chemiresistor microchemical sensor [J].
Ho, CK ;
Lohrstorfer, CF .
GROUND WATER MONITORING AND REMEDIATION, 2003, 23 (04) :85-90
[10]   Development of a surface acoustic wave sensor for in-situ monitoring of volatile organic compounds [J].
Ho, CK ;
Lindgren, ER ;
Rawlinson, KS ;
McGrath, LK ;
Wright, JL .
SENSORS, 2003, 3 (07) :236-247