Advanced oxidation processes: mechanistic aspects

被引:198
作者
von Sonntag, C. [1 ]
机构
[1] Max Planck Inst Bioanorgan Chem, Mulheim, Germany
关键词
AOP; Fenton reaction; hydrogen peroxide; hydroxyl radical; ozone; UV radiation;
D O I
10.2166/wst.2008.467
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The reactive intermediate in Advanced Oxidation Processes (AOPs) is the (OH)-O-center dot radical. It may be generated by various approaches such as the Fenton reaction ( Fe2+/H2O2), photo-Fenton reaction (Fe3+/H2O2/ hn), UV/H2O2, peroxone reaction (O-3/H2O2), O-3/UV, O-3/activated carbon, O-3/dissolved organic carbon (DOC) of water matrix, ionizing radiation, vacuum UV, and ultrasound. The underlying reactions and (OH)-O-center dot formation efficiencies are discussed. The key reactions of (OH)-O-center dot radicals also addressed in this review.
引用
收藏
页码:1015 / 1021
页数:7
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