New bifunctional organocatalysts based on (R,R)-cyclohexane-1,2-diamine for the asymmetric addition of nucleophiles to aldehydes

被引：1

作者：

Maleev, V. I. ^{[1
]}

Gugkaeva, Z. T. ^{[1
]}

Tsaloev, A. T. ^{[1
]}

Moskalenko, M. A. ^{[1
]}

Khrustalev, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 01期

关键词：

organocatalysis; asymmetric synthesis; aldehydes; trimethylsilyl cyanide; diethylzinc; (R,R)-cyclohexane-1,2-diamine; DYNAMIC KINETIC RESOLUTION; TRIMETHYLSILYL CYANIDE; ORGANOZINC REAGENTS; DERIVATIVES; CATALYSIS; TADDOLS; ALDOL;

D O I：

10.1007/s11172-012-0008-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The amide and sulfamide derivatives of (1R,2R)-N,N-diethylcyclohexane-1,2-diamine can serve as organocatalysts for addition of Me3SiCN and Et2Zn to aldehydes.

引用

页码：51 / 58

页数：8