A water-soluble, shape-persistent, mouldable supramolecular polymer with redox-responsiveness in the presence of a molecular chaperone

被引：19

作者：

Chi, Xiaodong ^{[1
]}

Xu, Donghua ^{[2
]}

Yan, Xuzhou ^{[1
]}

Chen, Jianzhuang ^{[1
]}

Zhang, Mingming ^{[1
]}

Hu, Bingjie ^{[3
]}

Yu, Yihua ^{[3
]}

Huang, Feihe ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, MOE Key Lab Macromol Synth & Functionalizat, Hangzhou 310027, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China

[3] E China Normal Univ, Shanghai Key Lab Magnet Resonance, Dept Phys, Shanghai 200062, Peoples R China

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 09期

基金：

中国国家自然科学基金;

关键词：

SELF-SORTING ORGANIZATION; HOST-GUEST INTERACTIONS; HYDROGEN-BONDING INTERACTIONS; TERMINATED POLYSTYRENE GUEST; CHARGE-TRANSFER INTERACTIONS; 2 HETERODITOPIC MONOMERS; CROWN-ETHER MOIETIES; PI-PI-STACKING; HOMODITOPIC MOLECULES; METAL COORDINATION;

D O I：

10.1039/c3py00201b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A water-soluble supramolecular polymer has been constructed from self-assembly of a heteroditopic monomer. It shows redox-responsiveness in the presence of a molecular chaperone. Furthermore, this supramolecular polymer material is shape-persistent and free-standing, which can be easily processed into various shapes. These unique features are all due to the dynamically reversible host-guest complexation and good mechanical properties of this supramolecular polymer, making it a platform to construct advanced and sophisticated materials. The formation of the supramolecular polymer was characterized by various techniques including two-dimensional diffusion-ordered NMR, scanning electron microscopy, and viscosity and rheology measurements.

引用

页码：2767 / 2772

页数：6

共 105 条

[1] Functional Supramolecular Polymers [J].

Aida, T. ;

Meijer, E. W. ;

Stupp, S. I. .

SCIENCE, 2012, 335 (6070) :813-817

[2]

[Anonymous], J AM CHEM SOC

[3]

Asakawa M, 1998, ANGEW CHEM INT EDIT, V37, P333, DOI 10.1002/(SICI)1521-3773(19980216)37:3<333::AID-ANIE333>3.0.CO

[4]

2-P

[5] An investigation of the complexation properties of cyclobis(paraquat-p-phenylene) in water [J].

Bria, Marc ;

Cooke, Graeme ;

Cooper, Alan ;

Garety, James F. ;

Hewage, Shanika Gunatilaka ;

Nutley, Margaret ;

Rabani, Gouher ;

Woisel, Patrice .

TETRAHEDRON LETTERS, 2007, 48 (02) :301-304

[6] A Healable Supramolecular Polymer Blend Based on Aromatic π-π Stacking and Hydrogen-Bonding Interactions [J].

Burattini, Stefano ;

Greenland, Barnaby W. ;

Merino, Daniel Hermida ;

Weng, Wengui ;

Seppala, Jonathan ;

Colquhoun, Howard M. ;

Hayes, Wayne ;

Mackay, Michael E. ;

Hamley, Ian W. ;

Rowan, Stuart J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) :12051-12058

[7] Opinion - Do we underestimate the importance of water in cell biology? [J].

Chaplin, Martin .

NATURE REVIEWS MOLECULAR CELL BIOLOGY, 2006, 7 (11) :861-866

[8] Dual-responsive crown ether-based supramolecular chain extended polymers [J].

Chen, Jianzhuang ;

Yan, Xuzhou ;

Chi, Xiaodong ;

Wu, Xiujuan ;

Zhang, Mingming ;

Han, Chengyou ;

Hu, Bingjie ;

Yu, Yihua ;

Huang, Feihe .

POLYMER CHEMISTRY, 2012, 3 (11) :3175-3179

[9] Adjustable supramolecular polymer microstructures fabricated by the breath figure method [J].

Chen, Jianzhuang ;

Yan, Xuzhou ;

Zhao, Qiaoling ;

Li, Lei ;

Huang, Feihe .

POLYMER CHEMISTRY, 2012, 3 (02) :458-462

[10] Multistimuli Responsive Supramolecular Cross-Linked Networks On the Basis of the Benzo-21-Crown-7/Secondary Ammonium Salt Recognition Motif [J].

Chen, Long ;

Tian, Yu-Kui ;

Ding, Yue ;

Tian, Yu-Jing ;

Wang, Feng .

MACROMOLECULES, 2012, 45 (20) :8412-8419

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