Selective naked eye and turn-on fluorescence for detection of D-3-HB based on an erbium complex

被引:3
作者
Guo, Chunlei [1 ]
Wang, Qingming [1 ,2 ]
Yang, Lei [1 ]
Wang, Hua [1 ]
Wang, Dong [1 ]
Tang, Xinhui [1 ]
机构
[1] Yancheng Teachers Univ, Jiangsu Prov Key Lab Coastal Wetland Bioresources, Sch Pharm, Yancheng 224051, Jiangsu, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
关键词
D-3-HB detection; Diabetic ketoacidosis; Probe; Er3+ complex; DIABETIC-KETOACIDOSIS; GLYCEMIC CONTROL; 3-HYDROXYBUTYRATE; SENSOR; MANAGEMENT; SYSTEM; ADOLESCENTS; CHILDREN; MELLITUS; INSULIN;
D O I
10.1016/j.jphotochem.2017.07.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel fluorescent sensor ([Er(C9H5O3)(2)](+), TP) has been designed and applied as a highly selective and sensitive fluorescent probe for recognition of D-3-HB in C2H5OH-water (v/v, 1/1) solution. The probe TP exhibits an excellent selectivity to D-3-HB over other examined metal ions, anions and some of the carboxylic acid series with a prominent fluorescence "turn-on" at 450 nm. Furthermore, the mechanism was illustrated by ESI - MS and H-1 - NMR. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:175 / 180
页数:6
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