Characteristics and performance of lanthanum gallate electrolyte-supported SOFC under ethanol steam and hydrogen

被引：19

作者：

Huang, Bo ^{[1
]}

Zu, Xin-Jian ^{[1
]}

Hu, Wan-Qi ^{[2
]}

Yu, Qing-Chun ^{[1
]}

Tu, Heng-Yong ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Inst Fuel Cell, Shanghai 200240, Peoples R China

[2] Chinese Acad Sci, Inst Proc Engn, Beijing 100864, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2009年 / 186卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Anode; Carbon deposition; Electrochemical impedance spectroscopy; LSGMC; Solid oxide fuel cell (SOFC); OXIDE FUEL-CELLS; DIRECT OXIDATION; CARBON DEPOSITION; ANODE; METHANE; CONDUCTIVITY; TEMPERATURE; PEROVSKITES; BEHAVIOR; GAS;

D O I：

10.1016/j.jpowsour.2008.09.068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study is focused on the electrochemical performance of perovskite-type materials based on doped LaGaO3. La0.8Sr0.2Ga0.8Mg0.2O3-delta (LSGM) and La0.8Sr0.2Ga0.8Mg0.115Co0.085O3-delta (LSGMC) were used as electrolytes and (Pr0.7Ca0.3)(0.9)MnO3 (PCM) and La0.75Sr0.25Cr0.25Mn0.5O3-delta (LSCM) as cathode and anode material, respectively. LSGM and LSGMC electrolytes were prepared by tape casting with a thickness of about 600 mu m. The performance of LSCM/LSGMC/PCM was slightly superior to that obtained on LSCM/LSGM/PCM at different temperatures in both humidified hydrogen and ethanol steam atmospheres, good values of power Output in LSCM/LSGMC/PCM were 182 and 169 mW cm(-2) using humidified hydrogen and ethanol steam as fuel, respectively, and oxygen as oxidant at 850 degrees C. Cell stability tests indicate no significant degradation in performance after 60h of cell testing when LSCM anode was exposed to ethanol steam at 750 degrees C. Almost no carbon deposits were detected after testing in ethanol steam at 750 degrees C for >60 h on the LSCM anodes, Suggesting that carbon deposition was limited during cell operation. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：29 / 36

页数：8

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