A flow microdevice for studying the initiation and propagation of a single pit

被引：9
作者：
Aouina, N. [2 ,3 ]
Balbaud-Celerier, F. [1 ]
Huet, F. [2 ,3 ]
Joiret, S. [2 ,3 ]
Perrot, H. [2 ,3 ]
Rouillard, F. [1 ]
Vivier, V. [2 ,3 ]
机构：
[1] CEA, DEN, DANS, DPC,SCCME,LECNA, F-91191 Gif Sur Yvette, France
[2] CNRS, UPR15, Lab Interfaces & Syst Electrochim, F-75005 Paris, France
[3] UPMC Univ Paris 06, LISE, UPR15, F-75005 Paris, France
来源：
CORROSION SCIENCE | 2012年 / 62卷
关键词：
Stainless steel; Pitting corrosion; Passive films; SCANNING ELECTROCHEMICAL MICROSCOPY; STAINLESS-STEEL; PITTING CORROSION; LOCALIZED CORROSION; CHLORIDE SOLUTION; MNS INCLUSIONS; SALT FILMS; GROWTH; IRON; LAYERS;
D O I：
10.1016/j.corsci.2012.05.002
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel experimental setup in which a glass microcapillary can be precisely positioned close to a metallic electrode has been developed to locally inject aggressive solutions at will. It has been used for studying the pitting corrosion of a 316L stainless steel in 0.5 M H2SO4 medium. The amount of chloride ions released by the capillary could be controlled and the analysis of the corrosion products by scanning electron microscopy and energy dispersive X-ray spectroscopy showed there was no selective dissolution of the 316L stainless steel. This device was shown to be an efficient tool for understanding localized corrosion. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1 / 4
页数：4
相关论文
共 29 条
  • [1] Impedance feedback control for scanning electrochemical microscopy
    Alpuche-Aviles, MA
    Wipf, DO
    [J]. ANALYTICAL CHEMISTRY, 2001, 73 (20) : 4873 - 4881
  • [2] Single pit initiation on 316L austenitic stainless steel using scanning electrochemical microscopy
    Aouina, N.
    Balbaud-Celerier, F.
    Huet, F.
    Joiret, S.
    Perrot, H.
    Rouillard, F.
    Vivier, V.
    [J]. ELECTROCHIMICA ACTA, 2011, 56 (24) : 8589 - 8596
  • [3] OCCURRENCE OF SALT FILMS DURING INITIATION AND GROWTH OF CORROSION PITS
    BECK, TR
    ALKIRE, RC
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (10) : 1662 - 1666
  • [4] Electrolyte-resistance change due to an insulating sphere in contact with a disk electrode
    Bouazaze, H.
    Fransaer, J.
    Huet, F.
    Rousseau, P.
    Vivier, V.
    [J]. ELECTROCHIMICA ACTA, 2010, 55 (05) : 1645 - 1655
  • [5] Burstein G.T., 1996, P ELECTROCHEM SOC, V95-15, P1
  • [6] THE NUCLEATION AND GROWTH OF CORROSION PITS ON STAINLESS-STEEL
    BURSTEIN, GT
    PISTORIUS, PC
    MATTIN, SP
    [J]. CORROSION SCIENCE, 1993, 35 (1-4) : 57 - 62
  • [7] Pit growth studies in stainless steel foils. I. Introduction and pit growth kinetics
    Ernst, P
    Newman, RC
    [J]. CORROSION SCIENCE, 2002, 44 (05) : 927 - 941
  • [8] The mechanism of lacy cover formation in pitting
    Ernst, P
    Laycock, NJ
    Moayed, MH
    Newman, RC
    [J]. CORROSION SCIENCE, 1997, 39 (06) : 1133 - 1136
  • [9] METASTABLE PITTING OF STAINLESS-STEEL
    FRANKEL, GS
    STOCKERT, L
    HUNKELER, F
    BOEHNI, H
    [J]. CORROSION, 1987, 43 (07) : 429 - 436
  • [10] Initiation of a local breakdown of passive film on iron due to chloride ions generated by a liquid-phase ion gun
    Fushimi, K
    Seo, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (11) : B450 - B456
123