A flow microdevice for studying the initiation and propagation of a single pit

被引:9
作者
Aouina, N. [2 ,3 ]
Balbaud-Celerier, F. [1 ]
Huet, F. [2 ,3 ]
Joiret, S. [2 ,3 ]
Perrot, H. [2 ,3 ]
Rouillard, F. [1 ]
Vivier, V. [2 ,3 ]
机构
[1] CEA, DEN, DANS, DPC,SCCME,LECNA, F-91191 Gif Sur Yvette, France
[2] CNRS, UPR15, Lab Interfaces & Syst Electrochim, F-75005 Paris, France
[3] UPMC Univ Paris 06, LISE, UPR15, F-75005 Paris, France
关键词
Stainless steel; Pitting corrosion; Passive films; SCANNING ELECTROCHEMICAL MICROSCOPY; STAINLESS-STEEL; PITTING CORROSION; LOCALIZED CORROSION; CHLORIDE SOLUTION; MNS INCLUSIONS; SALT FILMS; GROWTH; IRON; LAYERS;
D O I
10.1016/j.corsci.2012.05.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel experimental setup in which a glass microcapillary can be precisely positioned close to a metallic electrode has been developed to locally inject aggressive solutions at will. It has been used for studying the pitting corrosion of a 316L stainless steel in 0.5 M H2SO4 medium. The amount of chloride ions released by the capillary could be controlled and the analysis of the corrosion products by scanning electron microscopy and energy dispersive X-ray spectroscopy showed there was no selective dissolution of the 316L stainless steel. This device was shown to be an efficient tool for understanding localized corrosion. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
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