Silver Nanoparticle Formation under Hydrothermal Conditions from Trisilver Citrate

被引:0
|
作者
Yamamoto, Toshihiko [1 ]
Suzuki, Takanari [1 ]
Shishido, Masahiro [1 ]
Takesue, Masafumi [2 ]
Hata, Katsuhiko [2 ]
机构
[1] Yamagata Univ, Dept Chem & Chem Engn, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan
[2] Bando Chem Ind Ltd, New Business Promot Ctr, Chuo Ku, 4-6-6 Minamimachi, Kobe, Hyogo 6500047, Japan
关键词
Silver Nanoparticle; Liquid Phase Reduction; Trisilver Citrate; Reactive Crystallization; GROWTH; SIZE; REDUCTION; NANOWIRES; SHAPE;
D O I
10.1252/kakoronbunshu.45.60
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A novel route has been found for the formation of silver nanoparticles under hydrothermal conditions from the system of sodium citrate and silver nitrate via trisilver citrate, which is sparingly soluble in water. It was confirmed that the morphology of particulate and crystalline trisilver citrate formed by mixing aqueous solutions of sodium citrate and silver nitrate changed with holding time in water due to Ostwald ripening, and that silver nanorods rather than nanoparticles tended to form from ripened trisilver citrate.
引用
收藏
页码:60 / 65
页数:6
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