Unprecedented infinite lanthanide hydroxide ribbons [Ln3(μ3-OH)3]n6n+ in a 3-D metal-organic framework

被引：17
|
作者：
Sang, Rui-Li [1 ]
Xu, Li [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Chem, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 75期
基金：
中国国家自然科学基金;
关键词：
STRUCTURAL-CHARACTERIZATION; DYSPROSIUM TRIANGLES; MAGNET BEHAVIOR; DY-3; TRIANGLES; CLUSTERS; NETWORKS;
D O I：
10.1039/c3cc44181d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unprecedented infinite lanthanide hydroxide ribbons interconnected by Pra(2)biim(2-) (H(2)Pra(2)biim = 1'-di(propionic acid)-2,2'-biimidazole) into 3-D [Ln(3)(mu(3)-OH)(3)(Pra(2)biim)(3)(H2O)(2)](n center dot)4nH(2)O (Ln = Nd, Pr and La) have been achieved by utilizing the unique H(2)Pra(2)biim-Ln(3+) hydrolysis system. The Ln ... Ln antiferromagnetic coupling with magnetic anisotropy has been observed.
引用
收藏
页码：8344 / 8346
页数：3
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