Unprecedented infinite lanthanide hydroxide ribbons [Ln3(μ3-OH)3]n6n+ in a 3-D metal-organic framework

被引：17
|
作者：
Sang, Rui-Li [1 ]
Xu, Li [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Chem, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 75期
基金：
中国国家自然科学基金;
关键词：
STRUCTURAL-CHARACTERIZATION; DYSPROSIUM TRIANGLES; MAGNET BEHAVIOR; DY-3; TRIANGLES; CLUSTERS; NETWORKS;
D O I：
10.1039/c3cc44181d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unprecedented infinite lanthanide hydroxide ribbons interconnected by Pra(2)biim(2-) (H(2)Pra(2)biim = 1'-di(propionic acid)-2,2'-biimidazole) into 3-D [Ln(3)(mu(3)-OH)(3)(Pra(2)biim)(3)(H2O)(2)](n center dot)4nH(2)O (Ln = Nd, Pr and La) have been achieved by utilizing the unique H(2)Pra(2)biim-Ln(3+) hydrolysis system. The Ln ... Ln antiferromagnetic coupling with magnetic anisotropy has been observed.
引用
收藏
页码：8344 / 8346
页数：3
相关论文
共 50 条
  • [1] An anionic metal-organic framework based on infinite [In3(μ3-OH)2]n inorganic chains synthesized in ionic liquid
    Ji, Wen-Juan
    Zhai, Quan-Guo
    Li, Shu-Ni
    Jiang, Yu-Cheng
    Hu, Man-Cheng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 28 : 16 - 19
  • [2] Novel 3D lanthanide-organic frameworks with an unusual infinite nanosized ribbon [Ln3(μ3-OH)2(-CO2)6]n+ (Ln = Eu, Gd, Dy): syntheses, structures, luminescence, and magnetic properties
    Zhang, Hai-Juan
    Wang, Xiao-Zhu
    Zhu, Dun-Ru
    Song, You
    Xu, Yan
    Xu, Heng
    Shen, Xuan
    Gao, Ting
    Huang, Min-Xue
    CRYSTENGCOMM, 2011, 13 (07): : 2586 - 2592
  • [3] An unprecedented twofold interpenetrating (3,4)-connected 3-D metal-organic framework
    Hong, Seunghee
    Zou, Yang
    Moon, Dohyun
    Lah, Myoung Soo
    CHEMICAL COMMUNICATIONS, 2007, (17) : 1707 - 1709
  • [4] Enantiopure trinuclear lanthanide(III) complexes: Cooperative formation of Ln3(μ3-OH)2 core within the macrocycle
    Paluch, Marta
    Slepokura, Katarzyna
    Lis, Tadeusz
    Lisowski, Jerzy
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (01) : 92 - 95
  • [5] Metal-organic frameworks incorporating Cu3(μ3-OH) clusters
    Lysenko, Andrey B.
    Govor, Evgen V.
    Krautscheid, Harald
    Domasevitch, Konstantin V.
    DALTON TRANSACTIONS, 2006, 31 (31) : 3772 - 3776
  • [6] 3-D Lanthanide Metal-Organic Frameworks: Structure, Photoluminescence, and Magnetism
    Black, Cory A.
    Costa, Jose Sanchez
    Fu, Wen Tian
    Massera, Chiara
    Roubeau, Olivier
    Teat, Simon J.
    Aromi, Guillem
    Gamez, Patrick
    Reedijk, Jan
    INORGANIC CHEMISTRY, 2009, 48 (03) : 1062 - 1068
  • [7] Design and Construction of a Luminescent and Highly Stable 3D Metal-Organic Framework with a [Zn4(μ3-OH)2]6+ Core
    Khan, Sheeba
    Das, Prasenjit
    Mandal, Sanjay K.
    INORGANIC CHEMISTRY, 2020, 59 (07) : 4588 - 4600
  • [8] Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln7(μ3-OH)8]13+ Cluster
    Liu, Lianchao
    Shen, Chaojun
    Dong, Fangfang
    Wang, Wenjing
    Yuan, Daqiang
    CHINESE JOURNAL OF CHEMISTRY, 2016, 34 (02) : 210 - 214
  • [9] One novel near-infrared ytterbium metal-organic framework based on an unprecedented [Yb6(μ2-OH)2(μ3-OH)6]10+cluster
    Wen, Guo-Xuan
    Wang, Jian-Fang
    Wu, Xue-Qian
    Pan, Li-Qing
    Li, Dong-Sheng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 70 : 111 - 114
  • [10] Microporous metal-organic frameworks built on a Ln3 cluster as a six-connecting node
    Chen, XY
    Zhao, B
    Shi, W
    Xia, J
    Cheng, P
    Liao, DZ
    Yan, SP
    Jiang, ZH
    CHEMISTRY OF MATERIALS, 2005, 17 (11) : 2866 - 2874
12345