Unprecedented infinite lanthanide hydroxide ribbons [Ln3(μ3-OH)3]n6n+ in a 3-D metal-organic framework

被引：17

作者：

Sang, Rui-Li ^{[1
]}

Xu, Li ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Chem, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 75期

基金：

中国国家自然科学基金;

关键词：

STRUCTURAL-CHARACTERIZATION; DYSPROSIUM TRIANGLES; MAGNET BEHAVIOR; DY-3; TRIANGLES; CLUSTERS; NETWORKS;

D O I：

10.1039/c3cc44181d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unprecedented infinite lanthanide hydroxide ribbons interconnected by Pra(2)biim(2-) (H(2)Pra(2)biim = 1'-di(propionic acid)-2,2'-biimidazole) into 3-D [Ln(3)(mu(3)-OH)(3)(Pra(2)biim)(3)(H2O)(2)](n center dot)4nH(2)O (Ln = Nd, Pr and La) have been achieved by utilizing the unique H(2)Pra(2)biim-Ln(3+) hydrolysis system. The Ln ... Ln antiferromagnetic coupling with magnetic anisotropy has been observed.

引用

页码：8344 / 8346

页数：3

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