Conversion efficiency improvement mechanisms of polymer solar cells by balance electron-hole mobility using blended P3HT:PCBM:pentacene active layer

被引：28

作者：

Lee, Ching-Ting ^{[1
]}

Lee, Cheng-Hsin ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Inst Microelect, Dept Elect Engn, Res Ctr Energy Technol & Strategy, Tainan 701, Taiwan

来源：

ORGANIC ELECTRONICS | 2013年 / 14卷 / 08期

关键词：

Blended active layer; Carrier mobility balance; Polymer solar cells; Power conversion efficiency; Space-charge-limited current model; CHARGE-TRANSPORT; POLY(3-HEXYLTHIOPHENE); 3-HEXYLTHIOPHENE;

D O I：

10.1016/j.orgel.2013.04.038

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

To improve the power conversion efficiency of polymer solar cells, the blended P3HT:PCBM:pentacene active layer was used to balance hole-electron mobility and roughen surface. Using space-charged-limited current model to analyze the hole-only devices and the electron-only devices, the P3HT: PCBM: pentacene (weight ratio = 1:0.8:0.09) active layer exhibited balance hole-electron mobility. Compared with the power conversion efficiency of 3.46% of the conventional polymer solar cells using P3HT: PCBM (1: 0.8) active layer, the power conversion efficiency of 4.42% was obtained. In other words, the power conversion efficiency was improved about 27.5%. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：2046 / 2050

页数：5

共 23 条

[11] Improvement in power conversion efficiency by blending of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) into poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester active layer [J].

Lee, Myounghee ;

Kim, Yoojin ;

Lee, Sunae ;

An, Jongdeok ;

Im, Chan .

APPLIED PHYSICS LETTERS, 2012, 100 (22)

[12] Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene) [J].

Li, G ;

Shrotriya, V ;

Yao, Y ;

Yang, Y .

JOURNAL OF APPLIED PHYSICS, 2005, 98 (04)

[13] Hole transport in poly(phenylene vinylene)/methanofullerene bulk-heterojunction solar cells [J].

Melzer, C ;

Koop, EJ ;

Mihailetchi, VD ;

Blom, PWM .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) :865-870

[14] Charge transport and photocurrent generation in poly (3-hexylthiophene): Methanofullerene bulk-heterojunction solar cells [J].

Mihailetchi, VD ;

Xie, HX ;

de Boer, B ;

Koster, LJA ;

Blom, PWM .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (05) :699-708

[15] RETRACTED: Ambipolar pentacene field-effect transistors and inverters (Retracted article. See vol 298, pg 961, 2002) [J].

Schön, JH ;

Berg, S ;

Kloc, C ;

Batlogg, B .

SCIENCE, 2000, 287 (5455) :1022-1023

[16] Organic-based photovoltaics. toward low-cost power generation [J].

Shaheen, SE ;

Ginley, DS ;

Jabbour, GE .

MRS BULLETIN, 2005, 30 (01) :10-19

[17] Thermal analysis of active layer in organic thin-film transistors [J].

Shin, Moo Whan ;

Jang, Sun Ho .

ORGANIC ELECTRONICS, 2012, 13 (05) :767-770

[18] Synthesis and photovoltaic properties of low band gap quarterthiophenes-alt-diketopyrrolopyrroles polymers having high hole mobility [J].

Son, Seon Kyoung ;

Kim, Bong Soo ;

Lee, Chun-Young ;

Lee, Joong Suk ;

Cho, Jeong Ho ;

Ko, Min Jae ;

Lee, Doh-Kwon ;

Kim, Honggon ;

Choi, Dong Hoon ;

Kim, Kyungkon .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 104 :185-192

[19]

Therm D., 2012, IEEE PHOTONIC TECH L, V24, P912

[20] Room-temperature organic ferromagnetism in the crystalline poly (3-hexylthiophene): Phenyl-C61-butyric acid methyl ester blend film [J].

Yang, Bin ;

Xiao, Zhengguo ;

Yuan, Yongbo ;

Jayaraman, Tanjore V. ;

Shield, Jeffrey E. ;

Skomski, Ralph ;

Huang, Jinsong .

POLYMER, 2013, 54 (02) :490-494

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