Palladium-Catalyzed Regioselective C-H Acylation of Biaryl-2-amines

被引：17
作者：
Cai, Zhong-Jian [1 ]
Yang, Chao [1 ]
Wang, Shun-Yi [1 ]
Ji, Shun-Jun [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 16期
基金：
中国国家自然科学基金;
关键词：
DECARBOXYLATIVE ORTHO ACYLATION; ALPHA-OXOCARBOXYLIC ACIDS; TERT-BUTYL HYDROPEROXIDE; BOND ACTIVATION; CARBON-MONOXIDE; DIRECTING GROUP; FREE-AMINE; ORTHO-ARYLATION; ALKENYLATION; DERIVATIVES;
D O I：
10.1021/acs.joc.5b00962
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed efficient C-H acylation reaction of biaryl-2-amines and aromatic aldehydes is developed. This dehydrogenative cross-coupling protocol could furnish monoacylation and diacylation products in moderate to good yields with a broad substrate scope and good regioselectivity.
引用
收藏
页码：7928 / 7936
页数：9
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