Chemoselective alkynylation of N-sulfonylamides versus amides and carbamates - Synthesis of tetrahydropyrazines

被引：62

作者：

Aubineau, Thomas ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] CNRS, Lab Chim Organ Associe, F-75231 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 32期

关键词：

HETEROCYCLES;

D O I：

10.1039/c3cc40529j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemoselective alkynylation of N-sulfonylamides versus amides and carbamates using TMS-EBX as an alkynylating agent leads to the formation of non-symmetrical tetrahydropyrazines from orthogonally protected diamines.

引用

页码：3303 / 3305

页数：3

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